File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/jp100147g
- Scopus: eid_2-s2.0-77954270748
- WOS: WOS:000279282200019
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: CO2 Activation and total reduction on titanium(0001) surface
Title | CO<inf>2</inf> Activation and total reduction on titanium(0001) surface |
---|---|
Authors | |
Issue Date | 2010 |
Citation | Journal of Physical Chemistry C, 2010, v. 114, n. 26, p. 11456-11459 How to Cite? |
Abstract | From first-principles simulations, we identify that CO2is strongly activated and chemically adsorbed via both the carbon and the oxygen atoms and can totally dissociate on the Ti (0001) surface, under appropriate conditions, in contrast to relatively weak interactions of CO2with other transition metals reported previously. This strong activation is due to the relatively small work function or electronegativity of Ti. We postulate that a structure with a smaller work function provides greater activation for CO2. The findings point to new directions for the design of efficient Ti-based alloy catalysts for CO2capture and conversion. © 2010 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/262936 |
ISSN | 2023 Impact Factor: 3.3 2023 SCImago Journal Rankings: 0.957 |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Li, S. F. | - |
dc.contributor.author | Guo, Z. X. | - |
dc.date.accessioned | 2018-10-08T09:28:51Z | - |
dc.date.available | 2018-10-08T09:28:51Z | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Journal of Physical Chemistry C, 2010, v. 114, n. 26, p. 11456-11459 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | http://hdl.handle.net/10722/262936 | - |
dc.description.abstract | From first-principles simulations, we identify that CO2is strongly activated and chemically adsorbed via both the carbon and the oxygen atoms and can totally dissociate on the Ti (0001) surface, under appropriate conditions, in contrast to relatively weak interactions of CO2with other transition metals reported previously. This strong activation is due to the relatively small work function or electronegativity of Ti. We postulate that a structure with a smaller work function provides greater activation for CO2. The findings point to new directions for the design of efficient Ti-based alloy catalysts for CO2capture and conversion. © 2010 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Physical Chemistry C | - |
dc.title | CO<inf>2</inf> Activation and total reduction on titanium(0001) surface | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/jp100147g | - |
dc.identifier.scopus | eid_2-s2.0-77954270748 | - |
dc.identifier.volume | 114 | - |
dc.identifier.issue | 26 | - |
dc.identifier.spage | 11456 | - |
dc.identifier.epage | 11459 | - |
dc.identifier.eissn | 1932-7455 | - |
dc.identifier.isi | WOS:000279282200019 | - |
dc.identifier.issnl | 1932-7447 | - |