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Article: The Metal-Metal-to-Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer PdII-Isocyanide Complexes

TitleThe Metal-Metal-to-Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer PdII-Isocyanide Complexes
Authors
Wan, QTo, WPYang, CChe, CM
Keywordsintermolecular interactions
isocyanides
living supramolecular polymerization
MMLCT
palladium
Issue Date2018
PublisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie (International Edition), 2018, v. 57 n. 12, p. 3089-3093 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.201712249
Abstract© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Pincer PdII–isocyanide complexes are described that display intermolecular interactions and emissive3MMLCT excited states in aggregation state(s) at room temperature. The intermolecular PdII−PdIIand ligand–ligand interactions drive these complexes to undergo supramolecular polymerization in a living manner. Comprehensive spectroscopic studies reveal a pathway with a kinetic trap that can be modulated by changing the counteranion and metal atom. The PdIIsupramolecular assemblies comprise two different aggregation forms with only one to be emissive. DFT/TDDFT calculations lend support to the MMLCT absorption and emission of these pincer PdII–isocyanide aggregates.
Persistent Identifierhttp://hdl.handle.net/10722/256835
ISSN
1433-7851
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID
WOS:000426759900012

 

DC FieldValueLanguage
dc.contributor.authorWan, Q-
dc.contributor.authorTo, WP-
dc.contributor.authorYang, C-
dc.contributor.authorChe, CM-
dc.date.accessioned2018-07-24T08:58:04Z-
dc.date.available2018-07-24T08:58:04Z-
dc.date.issued2018-
dc.identifier.citationAngewandte Chemie (International Edition), 2018, v. 57 n. 12, p. 3089-3093-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/256835-
dc.description.abstract© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Pincer PdII–isocyanide complexes are described that display intermolecular interactions and emissive3MMLCT excited states in aggregation state(s) at room temperature. The intermolecular PdII−PdIIand ligand–ligand interactions drive these complexes to undergo supramolecular polymerization in a living manner. Comprehensive spectroscopic studies reveal a pathway with a kinetic trap that can be modulated by changing the counteranion and metal atom. The PdIIsupramolecular assemblies comprise two different aggregation forms with only one to be emissive. DFT/TDDFT calculations lend support to the MMLCT absorption and emission of these pincer PdII–isocyanide aggregates.-
dc.languageeng-
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home-
dc.relation.ispartofAngewandte Chemie (International Edition)-
dc.rightsThis is the peer reviewed version of the following article: Angewandte Chemie (International Edition), 2018, v. 57 n. 12, p. 3089-3093, which has been published in final form at |https://doi.org/10.1002/anie.201712249].This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving: http://olabout.wiley.com/WileyCDA/Section/id-828039.html#terms-
dc.subjectintermolecular interactions-
dc.subjectisocyanides-
dc.subjectliving supramolecular polymerization-
dc.subjectMMLCT-
dc.subjectpalladium-
dc.titleThe Metal-Metal-to-Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer PdII-Isocyanide Complexes-
dc.typeArticle-
dc.identifier.emailTo, WP: kevintwp@hku.hk-
dc.identifier.emailYang, C: yangchen@HKUCC-COM.hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityTo, WP=rp02410-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturepostprint-
dc.identifier.doi10.1002/anie.201712249-
dc.identifier.pmid29266599-
dc.identifier.scopuseid_2-s2.0-85041229341-
dc.identifier.hkuros287045-
dc.identifier.volume57-
dc.identifier.issue12-
dc.identifier.spage3089-
dc.identifier.epage3093-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000426759900012-
dc.publisher.placeGermany-
dc.identifier.issnl1433-7851-

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