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Article: Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes

TitleFormation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes
Authors
KeywordsN,S-heterocyclic carbene
Palladium
Thiazolium
Pyridyl
Anagostic
Issue Date2009
Citation
Journal of Organometallic Chemistry, 2009, v. 694, n. 3, p. 332-338 How to Cite?
AbstractMononuclear mixed-ligand complexes of Pd(II) containing a N,S-heterocyclic carbene (NSHC) with a secondary alkyl N-substituent and pyridyl ligand, with the general formula [PdI2(C10H11NS)L] (C10H11NS = 3-isopropylbenzothiazolin-2-ylidene; L = pyridine, 2-aminopyridine, 3-iodopyridine and 4-tert-butyl-pyridine) have been synthesized and characterized by X-ray single-crystal crystallography. Both solution and solid-state structures, as evident from their 1H NMR spectra and X-ray structures, show anagostic γ-hydrogen interactions of metal with methine of the substituent on the carbene or pyridyl ligand giving 5-membered-chelate-like structures. © 2008.
Persistent Identifierhttp://hdl.handle.net/10722/237589
ISSN
2023 Impact Factor: 2.1
2023 SCImago Journal Rankings: 0.359
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYen, Swee Kuan-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHuynh, Han Vinh-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:10:00Z-
dc.date.available2017-01-16T06:10:00Z-
dc.date.issued2009-
dc.identifier.citationJournal of Organometallic Chemistry, 2009, v. 694, n. 3, p. 332-338-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/237589-
dc.description.abstractMononuclear mixed-ligand complexes of Pd(II) containing a N,S-heterocyclic carbene (NSHC) with a secondary alkyl N-substituent and pyridyl ligand, with the general formula [PdI2(C10H11NS)L] (C10H11NS = 3-isopropylbenzothiazolin-2-ylidene; L = pyridine, 2-aminopyridine, 3-iodopyridine and 4-tert-butyl-pyridine) have been synthesized and characterized by X-ray single-crystal crystallography. Both solution and solid-state structures, as evident from their 1H NMR spectra and X-ray structures, show anagostic γ-hydrogen interactions of metal with methine of the substituent on the carbene or pyridyl ligand giving 5-membered-chelate-like structures. © 2008.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectN,S-heterocyclic carbene-
dc.subjectPalladium-
dc.subjectThiazolium-
dc.subjectPyridyl-
dc.subjectAnagostic-
dc.titleFormation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2008.10.048-
dc.identifier.scopuseid_2-s2.0-58249096372-
dc.identifier.volume694-
dc.identifier.issue3-
dc.identifier.spage332-
dc.identifier.epage338-
dc.identifier.isiWOS:000262608500004-
dc.identifier.issnl0022-328X-

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