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- Publisher Website: 10.1016/0022-328X(88)80415-7
- Scopus: eid_2-s2.0-5244287809
- WOS: WOS:A1988P478800006
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Article: Substituted metal carbonyls. VI. Convenient syntheses and characterizations of group 6 metal tricarbonyls with ligating α-diimine and triethyl phosphite
Title | Substituted metal carbonyls. VI. Convenient syntheses and characterizations of group 6 metal tricarbonyls with ligating α-diimine and triethyl phosphite |
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Authors | |
Issue Date | 1988 |
Citation | Journal of Organometallic Chemistry, 1988, v. 348, n. 3, p. 343-347 How to Cite? |
Abstract | Syntheses of group 6 mixed-ligand tricarbonyls M(CO3(NN)[P(OC2H5)3] (M = Cr, Mo, W; NN = 2,2′-bipyridyl and 1,10-phenanthroline) have been reinvestigated, simplified and the complexes spectroscopically characterized. The Cr and Mo complexes can be prepared conveniently from the tetracarbonyls M(CO)4(NN) at ambient temperature via a trimethylamine N-oxide-initiated decarbonylation pathway. All the tricarbonyls can also be satisfactorily prepared by refluxing a mixture of M(CO)6, (CH3)3NO, P(OC2H5)3 and the α-diimine ligand in a one-pot reaction. FT-IR, 1H and 31P NMR spectroscopic data are presented and discussed. © 1988. |
Persistent Identifier | http://hdl.handle.net/10722/237586 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Andy Hor, T. S. | - |
dc.contributor.author | Bte Rus, Siti Rohani | - |
dc.date.accessioned | 2017-01-16T06:09:58Z | - |
dc.date.available | 2017-01-16T06:09:58Z | - |
dc.date.issued | 1988 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 1988, v. 348, n. 3, p. 343-347 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10722/237586 | - |
dc.description.abstract | Syntheses of group 6 mixed-ligand tricarbonyls M(CO3(NN)[P(OC2H5)3] (M = Cr, Mo, W; NN = 2,2′-bipyridyl and 1,10-phenanthroline) have been reinvestigated, simplified and the complexes spectroscopically characterized. The Cr and Mo complexes can be prepared conveniently from the tetracarbonyls M(CO)4(NN) at ambient temperature via a trimethylamine N-oxide-initiated decarbonylation pathway. All the tricarbonyls can also be satisfactorily prepared by refluxing a mixture of M(CO)6, (CH3)3NO, P(OC2H5)3 and the α-diimine ligand in a one-pot reaction. FT-IR, 1H and 31P NMR spectroscopic data are presented and discussed. © 1988. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organometallic Chemistry | - |
dc.title | Substituted metal carbonyls. VI. Convenient syntheses and characterizations of group 6 metal tricarbonyls with ligating α-diimine and triethyl phosphite | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/0022-328X(88)80415-7 | - |
dc.identifier.scopus | eid_2-s2.0-5244287809 | - |
dc.identifier.volume | 348 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 343 | - |
dc.identifier.epage | 347 | - |
dc.identifier.isi | WOS:A1988P478800006 | - |
dc.identifier.issnl | 0022-328X | - |