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- Publisher Website: 10.1021/om0701322
- Scopus: eid_2-s2.0-34250747836
- WOS: WOS:000246764400002
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Article: A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization
Title | A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization |
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Authors | |
Issue Date | 2007 |
Citation | Organometallics, 2007, v. 26, n. 12, p. 2950-2952 How to Cite? |
Abstract | The unusual heterovalent bimetallic Ni1-Ni0 complex {[η-C5H4CH=N(C6F5)]Fe[η- C5H4PPh2]}2Ni2(Cl) (2) was isolated from the reaction between [η-C5H4CH= N(C6F5)]Fe[η-C5H4PPh 2] (1) and Ni(COD)2 in the presence of AlEtCl2 or AlCl3. Complex 2 has been crystallographically characterized and theoretically analyzed; it is catalytically active (TOF 90 500) and selective (91%) toward the formation of C4 oligomers from ethylene (300 psi) at 30 °C, the only other significant isomer formed being C6. © 2007 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/237575 |
ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.654 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Weng, Zhiqiang | - |
dc.contributor.author | Teo, Shihui | - |
dc.contributor.author | Liu, Zhi Pan | - |
dc.contributor.author | Andy Hor, T. S. | - |
dc.date.accessioned | 2017-01-16T06:09:54Z | - |
dc.date.available | 2017-01-16T06:09:54Z | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | Organometallics, 2007, v. 26, n. 12, p. 2950-2952 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10722/237575 | - |
dc.description.abstract | The unusual heterovalent bimetallic Ni1-Ni0 complex {[η-C5H4CH=N(C6F5)]Fe[η- C5H4PPh2]}2Ni2(Cl) (2) was isolated from the reaction between [η-C5H4CH= N(C6F5)]Fe[η-C5H4PPh 2] (1) and Ni(COD)2 in the presence of AlEtCl2 or AlCl3. Complex 2 has been crystallographically characterized and theoretically analyzed; it is catalytically active (TOF 90 500) and selective (91%) toward the formation of C4 oligomers from ethylene (300 psi) at 30 °C, the only other significant isomer formed being C6. © 2007 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Organometallics | - |
dc.title | A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/om0701322 | - |
dc.identifier.scopus | eid_2-s2.0-34250747836 | - |
dc.identifier.volume | 26 | - |
dc.identifier.issue | 12 | - |
dc.identifier.spage | 2950 | - |
dc.identifier.epage | 2952 | - |
dc.identifier.isi | WOS:000246764400002 | - |
dc.identifier.issnl | 0276-7333 | - |