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Article: Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S)2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)

TitleSulfide-bridged aggregates from the metalloligand [Pt2(μ-S)2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)
Authors
Bridson, James H.Henderson, WilliamNicholson, Brian K.Andy Hor, T. S.
KeywordsZinc complexes
Cobalt complexes
Platinum complexes
Sulfide aggregates
Issue Date2006
Citation
Inorganica Chimica Acta, 2006, v. 359, n. 2, p. 680-684 How to Cite?
DOI: http://dx.doi.org/10.1016/j.ica.2005.06.082
AbstractReaction of [Pt2(μ-S)2(PPh3) 4] with a range of zinc(II) and cobalt(II) complexes ML2, where L is a β-diketonate ligand CH3COCHCOCH3, PhCOCHCOPh, CF3COCHCOTh (Th = 2-thienyl)] permits the synthesis of adducts [Pt2(μ-S)2(PPh3) 4M(diketonate)]+, isolated as their BPh4- salts in moderate yields. The cobalt and zinc acetylacetonate complexes were characterised by single-crystal X-ray diffraction studies, which reveal isomorphous structures, with tetrahedral heterometal centres. © 2005 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/237569
ISSN
0020-1693
2023 Impact Factor: 2.7
2023 SCImago Journal Rankings: 0.386
ISI Accession Number ID
WOS:000234772000035

 

DC FieldValueLanguage
dc.contributor.authorBridson, James H.-
dc.contributor.authorHenderson, William-
dc.contributor.authorNicholson, Brian K.-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:09:51Z-
dc.date.available2017-01-16T06:09:51Z-
dc.date.issued2006-
dc.identifier.citationInorganica Chimica Acta, 2006, v. 359, n. 2, p. 680-684-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/237569-
dc.description.abstractReaction of [Pt2(μ-S)2(PPh3) 4] with a range of zinc(II) and cobalt(II) complexes ML2, where L is a β-diketonate ligand CH3COCHCOCH3, PhCOCHCOPh, CF3COCHCOTh (Th = 2-thienyl)] permits the synthesis of adducts [Pt2(μ-S)2(PPh3) 4M(diketonate)]+, isolated as their BPh4- salts in moderate yields. The cobalt and zinc acetylacetonate complexes were characterised by single-crystal X-ray diffraction studies, which reveal isomorphous structures, with tetrahedral heterometal centres. © 2005 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganica Chimica Acta-
dc.subjectZinc complexes-
dc.subjectCobalt complexes-
dc.subjectPlatinum complexes-
dc.subjectSulfide aggregates-
dc.titleSulfide-bridged aggregates from the metalloligand [Pt2(μ-S)2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2005.06.082-
dc.identifier.scopuseid_2-s2.0-29844453106-
dc.identifier.volume359-
dc.identifier.issue2-
dc.identifier.spage680-
dc.identifier.epage684-
dc.identifier.isiWOS:000234772000035-
dc.identifier.issnl0020-1693-

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