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- Publisher Website: 10.1016/0022-328X(90)85102-5
- Scopus: eid_2-s2.0-0038957457
- WOS: WOS:A1990DQ86200009
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Article: Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes
| Title | Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes |
|---|---|
| Authors | |
| Issue Date | 1990 |
| Citation | Journal of Organometallic Chemistry, 1990, v. 390, n. 3, p. 345-350 How to Cite? |
| Abstract | The potential of Fe(CO)4(η1-dppf) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) as a precursor for heterometallic species is fully expanded in the synthesis of (OC)4Fe(μ-dppf)Cr(CO)5, (OC)4Fe(μ-dppf)W(CO)5, and (OC)4Fe(μ-dppf)Mn2(CO)9, all of which have been characterized by IR, NMR (1H and 31P) and elemental analyses. The low energy requirement of TMNO (Me3NO · 2H2O)decarbonylation allows the formation of monosubstituted Mn2(CO)10 as the major product. This aspect is further substantiated by the isolation of Mn4(CO)18(μ-dppf) in which the single bridging of a diphosphine group between two Mn2(CO)9 moieties is unprecedented. © 1990. |
| Persistent Identifier | http://hdl.handle.net/10722/237557 |
| ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Andy Hor, T. S. | - |
| dc.contributor.author | Phang, Lai Tee | - |
| dc.date.accessioned | 2017-01-16T06:09:44Z | - |
| dc.date.available | 2017-01-16T06:09:44Z | - |
| dc.date.issued | 1990 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 1990, v. 390, n. 3, p. 345-350 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/237557 | - |
| dc.description.abstract | The potential of Fe(CO)4(η1-dppf) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) as a precursor for heterometallic species is fully expanded in the synthesis of (OC)4Fe(μ-dppf)Cr(CO)5, (OC)4Fe(μ-dppf)W(CO)5, and (OC)4Fe(μ-dppf)Mn2(CO)9, all of which have been characterized by IR, NMR (1H and 31P) and elemental analyses. The low energy requirement of TMNO (Me3NO · 2H2O)decarbonylation allows the formation of monosubstituted Mn2(CO)10 as the major product. This aspect is further substantiated by the isolation of Mn4(CO)18(μ-dppf) in which the single bridging of a diphosphine group between two Mn2(CO)9 moieties is unprecedented. © 1990. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.title | Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/0022-328X(90)85102-5 | - |
| dc.identifier.scopus | eid_2-s2.0-0038957457 | - |
| dc.identifier.volume | 390 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.spage | 345 | - |
| dc.identifier.epage | 350 | - |
| dc.identifier.isi | WOS:A1990DQ86200009 | - |
| dc.identifier.issnl | 0022-328X | - |