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Article: Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes

TitleSubstituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes
Authors
Issue Date1990
Citation
Journal of Organometallic Chemistry, 1990, v. 390, n. 3, p. 345-350 How to Cite?
AbstractThe potential of Fe(CO)4(η1-dppf) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) as a precursor for heterometallic species is fully expanded in the synthesis of (OC)4Fe(μ-dppf)Cr(CO)5, (OC)4Fe(μ-dppf)W(CO)5, and (OC)4Fe(μ-dppf)Mn2(CO)9, all of which have been characterized by IR, NMR (1H and 31P) and elemental analyses. The low energy requirement of TMNO (Me3NO · 2H2O)decarbonylation allows the formation of monosubstituted Mn2(CO)10 as the major product. This aspect is further substantiated by the isolation of Mn4(CO)18(μ-dppf) in which the single bridging of a diphosphine group between two Mn2(CO)9 moieties is unprecedented. © 1990.
Persistent Identifierhttp://hdl.handle.net/10722/237557
ISSN
2020 Impact Factor: 2.369
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorAndy Hor, T. S.-
dc.contributor.authorPhang, Lai Tee-
dc.date.accessioned2017-01-16T06:09:44Z-
dc.date.available2017-01-16T06:09:44Z-
dc.date.issued1990-
dc.identifier.citationJournal of Organometallic Chemistry, 1990, v. 390, n. 3, p. 345-350-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/237557-
dc.description.abstractThe potential of Fe(CO)4(η1-dppf) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) as a precursor for heterometallic species is fully expanded in the synthesis of (OC)4Fe(μ-dppf)Cr(CO)5, (OC)4Fe(μ-dppf)W(CO)5, and (OC)4Fe(μ-dppf)Mn2(CO)9, all of which have been characterized by IR, NMR (1H and 31P) and elemental analyses. The low energy requirement of TMNO (Me3NO · 2H2O)decarbonylation allows the formation of monosubstituted Mn2(CO)10 as the major product. This aspect is further substantiated by the isolation of Mn4(CO)18(μ-dppf) in which the single bridging of a diphosphine group between two Mn2(CO)9 moieties is unprecedented. © 1990.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.titleSubstituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0022-328X(90)85102-5-
dc.identifier.scopuseid_2-s2.0-0038957457-
dc.identifier.volume390-
dc.identifier.issue3-
dc.identifier.spage345-
dc.identifier.epage350-
dc.identifier.isiWOS:A1990DQ86200009-
dc.identifier.issnl0022-328X-

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