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Article: Substituted metal carbonyls. XVI. X-ray photoelectron spectroscopic differentiation of chemically distinct phosphorus environments in unidentate complexes of 1,1′-bis(diphenylphosphino)ferrocene

TitleSubstituted metal carbonyls. XVI. X-ray photoelectron spectroscopic differentiation of chemically distinct phosphorus environments in unidentate complexes of 1,1′-bis(diphenylphosphino)ferrocene
Authors
Issue Date1991
Citation
Journal of Organometallic Chemistry, 1991, v. 407, n. 3, p. 353-357 How to Cite?
AbstractX-ray photoelectron spectra of M(CO)n(η1-dppf) (n = 5, M Cr, 1, Mo, 2, W, 3; n = 4, M = Fe, 4), (OC)4Fe(η-dppf)Mo(CO)5, 5, (OC)5M(η-dppf)M(CO)5 (M Cr, 6, Mo, 7, W, 8) and 1,1′bis(diphenylphosphino) ferrocene (dppf), 9, suggested that the technique can be diagnostic for pendant and coordinated phosphines, and, in heterometallic cases, be used to differentiated phosphines bound to different metals. The resolution of the P(2p) bands permits a measurement of the relative binding energies for chemically distinct phosphorus sites in the same complex thus eliminating complications in calibration as well as sample charging problems normally associated with X-ray photoelectron spectroscopy in comparative studies. © 1991.
Persistent Identifierhttp://hdl.handle.net/10722/237545
ISSN
2020 Impact Factor: 2.369
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChan, Hardy S O-
dc.contributor.authorAndy Hor, T. S.-
dc.contributor.authorPhang, Lai Tee-
dc.contributor.authorTan, Kuang Lee-
dc.date.accessioned2017-01-16T06:09:38Z-
dc.date.available2017-01-16T06:09:38Z-
dc.date.issued1991-
dc.identifier.citationJournal of Organometallic Chemistry, 1991, v. 407, n. 3, p. 353-357-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/237545-
dc.description.abstractX-ray photoelectron spectra of M(CO)n(η1-dppf) (n = 5, M Cr, 1, Mo, 2, W, 3; n = 4, M = Fe, 4), (OC)4Fe(η-dppf)Mo(CO)5, 5, (OC)5M(η-dppf)M(CO)5 (M Cr, 6, Mo, 7, W, 8) and 1,1′bis(diphenylphosphino) ferrocene (dppf), 9, suggested that the technique can be diagnostic for pendant and coordinated phosphines, and, in heterometallic cases, be used to differentiated phosphines bound to different metals. The resolution of the P(2p) bands permits a measurement of the relative binding energies for chemically distinct phosphorus sites in the same complex thus eliminating complications in calibration as well as sample charging problems normally associated with X-ray photoelectron spectroscopy in comparative studies. © 1991.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.titleSubstituted metal carbonyls. XVI. X-ray photoelectron spectroscopic differentiation of chemically distinct phosphorus environments in unidentate complexes of 1,1′-bis(diphenylphosphino)ferrocene-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0022-328X(91)86313-F-
dc.identifier.scopuseid_2-s2.0-0001757694-
dc.identifier.volume407-
dc.identifier.issue3-
dc.identifier.spage353-
dc.identifier.epage357-
dc.identifier.isiWOS:A1991FK75700008-
dc.identifier.issnl0022-328X-

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