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Article: Substituted metal carbonyls. Part 25: Unidentate, intramolecular, and intermolecular bridging modes of 1,1′-bis(diphenylphosphino)ferrocene in M3 S2 (CO)9 (M = Fe, Ru) cluster derivatives
| Title | Substituted metal carbonyls. Part 25: Unidentate, intramolecular, and intermolecular bridging modes of 1,1′-bis(diphenylphosphino)ferrocene in M<inf>3</inf>S<inf>2</inf>(CO)<inf>9</inf> (M = Fe, Ru) cluster derivatives |
|---|---|
| Authors | |
| Issue Date | 1994 |
| Citation | Journal of Cluster Science, 1994, v. 5, n. 2, p. 327-340 How to Cite? |
| Abstract | Carbonyl exchange of Fe3(μ3-S)2(CO)9 wioth 1,1′-bis(diphenylphosphino)ferrocene (dppf) in refluxing THF gives a cluster ligand with a pendant phosphine moiety, Fe3(μ3-S)2(CO)8 (gn1-Ph2PlC5H4)Fe(C5H4)P4 MePh2)]1-, 4. Addition of 1 to AuCl(SMe2) gives ClAu(μ-dppf) Fe4(μ3-S)2(CO)8, 8 (45%). Spectroscopic evidence is also obtained for (OC)8 (μ3-S)2Fe3(μ-dppf) Os3(CO)11, 7 and PdCl2[(μ-dppf)Fe3(μ3-D)2(CO)8]2, 9, from 1 and Os3(CO)11(CH3CN) and PdCl2CN)2, respectively. Crystal data dor 3: space group P21/n, a = 10.891(3) Å, b = 19.939(3) Å, c = 20.443(2) Å, β 100.17(2)°. Z = 4, 3917 reflections, R = 0.049. © 1994 Plenum Publishing Corporation. |
| Persistent Identifier | http://hdl.handle.net/10722/237541 |
| ISSN | 2021 Impact Factor: 3.447 2020 SCImago Journal Rankings: 0.405 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Fang, Zhi Gang | - |
| dc.contributor.author | Wen, Yuh Sheng | - |
| dc.contributor.author | Wong, Raymond K L | - |
| dc.contributor.author | Ng, Siu Choon | - |
| dc.contributor.author | Liu, Ling Kang | - |
| dc.contributor.author | Andy Hor, T. S. | - |
| dc.date.accessioned | 2017-01-16T06:09:35Z | - |
| dc.date.available | 2017-01-16T06:09:35Z | - |
| dc.date.issued | 1994 | - |
| dc.identifier.citation | Journal of Cluster Science, 1994, v. 5, n. 2, p. 327-340 | - |
| dc.identifier.issn | 1040-7278 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/237541 | - |
| dc.description.abstract | Carbonyl exchange of Fe3(μ3-S)2(CO)9 wioth 1,1′-bis(diphenylphosphino)ferrocene (dppf) in refluxing THF gives a cluster ligand with a pendant phosphine moiety, Fe3(μ3-S)2(CO)8 (gn1-Ph2PlC5H4)Fe(C5H4)P4 MePh2)]1-, 4. Addition of 1 to AuCl(SMe2) gives ClAu(μ-dppf) Fe4(μ3-S)2(CO)8, 8 (45%). Spectroscopic evidence is also obtained for (OC)8 (μ3-S)2Fe3(μ-dppf) Os3(CO)11, 7 and PdCl2[(μ-dppf)Fe3(μ3-D)2(CO)8]2, 9, from 1 and Os3(CO)11(CH3CN) and PdCl2CN)2, respectively. Crystal data dor 3: space group P21/n, a = 10.891(3) Å, b = 19.939(3) Å, c = 20.443(2) Å, β 100.17(2)°. Z = 4, 3917 reflections, R = 0.049. © 1994 Plenum Publishing Corporation. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Cluster Science | - |
| dc.title | Substituted metal carbonyls. Part 25: Unidentate, intramolecular, and intermolecular bridging modes of 1,1′-bis(diphenylphosphino)ferrocene in M<inf>3</inf>S<inf>2</inf>(CO)<inf>9</inf> (M = Fe, Ru) cluster derivatives | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1007/BF01170716 | - |
| dc.identifier.scopus | eid_2-s2.0-0000593432 | - |
| dc.identifier.volume | 5 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | 327 | - |
| dc.identifier.epage | 340 | - |
| dc.identifier.eissn | 1572-8862 | - |
| dc.identifier.issnl | 1040-7278 | - |