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Conference Paper: Hybrid 1,2,3-Triazole Supported CuII Complexes: Tuning Assembly and Weak Interaction-Driven Crystal Growth
Title | Hybrid 1,2,3-Triazole Supported CuII Complexes: Tuning Assembly and Weak Interaction-Driven Crystal Growth |
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Authors | |
Issue Date | 2016 |
Publisher | CSIRO Publishing. The Journal's web site is located at http://www.publish.csiro.au/nid/51.htm |
Citation | The 5th Molecular Materials Meeting (M3): The Next 50 Years in Materials Research, Singapore, 3-5 August 2015. In Australian Journal of Chemistry, 2016, v. 69, n. 4, p. 372-378 How to Cite? |
Abstract | © 2016 CSIRO.Two new dinuclear CuII complexes [Cu2Cl4(L1)2] (1) and [Cu2Cl4(L2)2] (2) (L1=2-((4-(2-(cyclopentylthio)ethyl)-1H-1,2,3-triazol-1-yl)methyl)pyridine; L2=2-((4-(pyridin-2-yl)-1H-1,2,3-triazol-1-yl)methyl)benzonitrile) were synthesised and characterised by single-crystal X-ray diffraction (XRD), powder XRD, thermogravimetric analysis, elemental analysis and IR measurements. The picolyl-triazole ligand L1 coordinates in a chelate-bridging mode forming a dinuclear structure 1. The more rigid pyridyl-triazole ligand L2 chelates only, generating a chloride-bridged dinuclear complex 2. Both crystals of complexes 1 and 2 show dominant plate shapes that correlate with weak 2D H-bonding interactions in the lattice. A mononuclear structure (3, [CuCl2(L3)2]6H2O, L3 = 3-((4-(pyridin-2-yl)-1H-1,2,3-triazol-1-yl)methyl)benzonitrile) yields block shape crystals that correlate with 3D H-bonding interactions. This study demonstrates tunable assembly at the molecular level and the relationship of crystal shape with weak lattice interactions. |
Persistent Identifier | http://hdl.handle.net/10722/237527 |
ISSN | 2023 Impact Factor: 1.0 2023 SCImago Journal Rankings: 0.267 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Bai, Shi Qiang | - |
dc.contributor.author | Jiang, Lu | - |
dc.contributor.author | Young, David James | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2017-01-16T06:09:28Z | - |
dc.date.available | 2017-01-16T06:09:28Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | The 5th Molecular Materials Meeting (M3): The Next 50 Years in Materials Research, Singapore, 3-5 August 2015. In Australian Journal of Chemistry, 2016, v. 69, n. 4, p. 372-378 | - |
dc.identifier.issn | 0004-9425 | - |
dc.identifier.uri | http://hdl.handle.net/10722/237527 | - |
dc.description.abstract | © 2016 CSIRO.Two new dinuclear CuII complexes [Cu2Cl4(L1)2] (1) and [Cu2Cl4(L2)2] (2) (L1=2-((4-(2-(cyclopentylthio)ethyl)-1H-1,2,3-triazol-1-yl)methyl)pyridine; L2=2-((4-(pyridin-2-yl)-1H-1,2,3-triazol-1-yl)methyl)benzonitrile) were synthesised and characterised by single-crystal X-ray diffraction (XRD), powder XRD, thermogravimetric analysis, elemental analysis and IR measurements. The picolyl-triazole ligand L1 coordinates in a chelate-bridging mode forming a dinuclear structure 1. The more rigid pyridyl-triazole ligand L2 chelates only, generating a chloride-bridged dinuclear complex 2. Both crystals of complexes 1 and 2 show dominant plate shapes that correlate with weak 2D H-bonding interactions in the lattice. A mononuclear structure (3, [CuCl2(L3)2]6H2O, L3 = 3-((4-(pyridin-2-yl)-1H-1,2,3-triazol-1-yl)methyl)benzonitrile) yields block shape crystals that correlate with 3D H-bonding interactions. This study demonstrates tunable assembly at the molecular level and the relationship of crystal shape with weak lattice interactions. | - |
dc.language | eng | - |
dc.publisher | CSIRO Publishing. The Journal's web site is located at http://www.publish.csiro.au/nid/51.htm | - |
dc.relation.ispartof | Australian Journal of Chemistry | - |
dc.title | Hybrid 1,2,3-Triazole Supported CuII Complexes: Tuning Assembly and Weak Interaction-Driven Crystal Growth | - |
dc.type | Conference_Paper | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1071/CH15650 | - |
dc.identifier.scopus | eid_2-s2.0-84964388608 | - |
dc.identifier.hkuros | 285677 | - |
dc.identifier.volume | 69 | - |
dc.identifier.issue | 4 | - |
dc.identifier.spage | 372 | - |
dc.identifier.epage | 378 | - |
dc.identifier.eissn | 1445-0038 | - |
dc.identifier.isi | WOS:000374182400003 | - |
dc.publisher.place | Australia | - |
dc.identifier.issnl | 0004-9425 | - |