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Article: Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates

TitleMetal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates
Authors
Armaghan, MahsaShang, Xiu JuanYuan, Yan QiuYoung, David J.Zhang, Wen HuaHor, T. S AndyLang, Jian Ping
Keywordsmetal-organic frameworks
metal-carboxylate zwitterions
photoluminescence
Issue Date2015
Citation
ChemPlusChem, 2015, v. 80, n. 8, p. 1231-1234 How to Cite?
DOI: http://dx.doi.org/10.1002/cplu.201500134
Abstract© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)2 in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups. Emissive intermediates: Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)2 in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form emissive metal-carboxylate zwitterions (see picture). In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs.
Persistent Identifierhttp://hdl.handle.net/10722/219800
ISI Accession Number ID
WOS:000359086900006

 

DC FieldValueLanguage
dc.contributor.authorArmaghan, Mahsa-
dc.contributor.authorShang, Xiu Juan-
dc.contributor.authorYuan, Yan Qiu-
dc.contributor.authorYoung, David J.-
dc.contributor.authorZhang, Wen Hua-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorLang, Jian Ping-
dc.date.accessioned2015-09-23T02:57:59Z-
dc.date.available2015-09-23T02:57:59Z-
dc.date.issued2015-
dc.identifier.citationChemPlusChem, 2015, v. 80, n. 8, p. 1231-1234-
dc.identifier.urihttp://hdl.handle.net/10722/219800-
dc.description.abstract© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO<inf>3</inf>)<inf>2</inf> in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups. Emissive intermediates: Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO<inf>3</inf>)<inf>2</inf> in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form emissive metal-carboxylate zwitterions (see picture). In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs.-
dc.languageeng-
dc.relation.ispartofChemPlusChem-
dc.subjectmetal-organic frameworks-
dc.subjectmetal-carboxylate zwitterions-
dc.subjectphotoluminescence-
dc.titleMetal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/cplu.201500134-
dc.identifier.scopuseid_2-s2.0-84938421485-
dc.identifier.hkuros285691-
dc.identifier.volume80-
dc.identifier.issue8-
dc.identifier.spage1231-
dc.identifier.epage1234-
dc.identifier.eissn2192-6506-
dc.identifier.isiWOS:000359086900006-
dc.identifier.issnl2192-6506-

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