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- Publisher Website: 10.1021/ic301527b
- Scopus: eid_2-s2.0-84869443870
- PMID: 23106491
- WOS: WOS:000311173700002
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Article: General one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates
Title | General one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates |
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Authors | |
Issue Date | 2012 |
Citation | Inorganic Chemistry, 2012, v. 51, n. 22, p. 12059-12061 How to Cite? |
Abstract | A new family of Co/rare-earth intermetallic cubane aggregates [Co 3Ln(hmp) 4(OAc) 5H 2O] (Ln = Dy, Ho, Er, Tm, Yb, Y) have been synthesized by self-assembly. Single-crystal X-ray diffraction analysis revealed that they are remarkably isostructural in showing a common [Co 3Ln] core. Magnetic studies showed that the Dy, Er, Tm, Yb, and Y complexes are ferromagnetic. The Dy complex exhibits the largest magnetocaloric effect (-ΔS m = 12.58 J kg -1 K -1), which can be attributed to the large magnetic density of Dy III. © 2012 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/219680 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wang, Pei | - |
dc.contributor.author | Shannigrahi, Santiranjan | - |
dc.contributor.author | Yakovlev, Nikolai L. | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:42Z | - |
dc.date.available | 2015-09-23T02:57:42Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | Inorganic Chemistry, 2012, v. 51, n. 22, p. 12059-12061 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219680 | - |
dc.description.abstract | A new family of Co/rare-earth intermetallic cubane aggregates [Co 3Ln(hmp) 4(OAc) 5H 2O] (Ln = Dy, Ho, Er, Tm, Yb, Y) have been synthesized by self-assembly. Single-crystal X-ray diffraction analysis revealed that they are remarkably isostructural in showing a common [Co 3Ln] core. Magnetic studies showed that the Dy, Er, Tm, Yb, and Y complexes are ferromagnetic. The Dy complex exhibits the largest magnetocaloric effect (-ΔS m = 12.58 J kg -1 K -1), which can be attributed to the large magnetic density of Dy III. © 2012 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Inorganic Chemistry | - |
dc.title | General one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ic301527b | - |
dc.identifier.pmid | 23106491 | - |
dc.identifier.scopus | eid_2-s2.0-84869443870 | - |
dc.identifier.volume | 51 | - |
dc.identifier.issue | 22 | - |
dc.identifier.spage | 12059 | - |
dc.identifier.epage | 12061 | - |
dc.identifier.isi | WOS:000311173700002 | - |
dc.identifier.issnl | 0020-1669 | - |