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- Publisher Website: 10.1016/0022-328X(94)87092-6
- Scopus: eid_2-s2.0-43949159966
- WOS: WOS:A1994PD27600019
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Article: Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]
| Title | Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2] |
|---|---|
| Authors | |
| Keywords | Platinum Sulfide Diphosphine Phosphine Ferrocene Thiolate |
| Issue Date | 1994 |
| Citation | Journal of Organometallic Chemistry, 1994, v. 476, n. 2, p. c32-c34 How to Cite? |
| Abstract | Reaction of PtCl2(dppf) or [Pt(CH3CN)2(dppf)][BF4]2 with Na2S gives [Pt(μ-S)(dppf)]2. This bridging thio complex rapidly undergoes nucleophilic attack on CH2Cl2 to give [Pt2(μ-S)(μ-SCH2Cl)(dppf)2]Cl, which cleanly converts into [Pt(SCH2Cl)2(dppf)] with liberation of [PtCl2(dppf)]. These reactions effectively complete a cycle which yields a chloromethanethiolato complex from Na2S and CH2Cl2 via a thio complex. © 1994. |
| Persistent Identifier | http://hdl.handle.net/10722/219573 |
| ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Meisheng, Zhou | - |
| dc.contributor.author | Choon, Fui Lam | - |
| dc.contributor.author | Mok, K. F. | - |
| dc.contributor.author | Pak-Hing, Leung | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:26Z | - |
| dc.date.available | 2015-09-23T02:57:26Z | - |
| dc.date.issued | 1994 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 1994, v. 476, n. 2, p. c32-c34 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219573 | - |
| dc.description.abstract | Reaction of PtCl2(dppf) or [Pt(CH3CN)2(dppf)][BF4]2 with Na2S gives [Pt(μ-S)(dppf)]2. This bridging thio complex rapidly undergoes nucleophilic attack on CH2Cl2 to give [Pt2(μ-S)(μ-SCH2Cl)(dppf)2]Cl, which cleanly converts into [Pt(SCH2Cl)2(dppf)] with liberation of [PtCl2(dppf)]. These reactions effectively complete a cycle which yields a chloromethanethiolato complex from Na2S and CH2Cl2 via a thio complex. © 1994. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.subject | Platinum | - |
| dc.subject | Sulfide | - |
| dc.subject | Diphosphine | - |
| dc.subject | Phosphine | - |
| dc.subject | Ferrocene | - |
| dc.subject | Thiolate | - |
| dc.title | Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2] | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/0022-328X(94)87092-6 | - |
| dc.identifier.scopus | eid_2-s2.0-43949159966 | - |
| dc.identifier.volume | 476 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | c32 | - |
| dc.identifier.epage | c34 | - |
| dc.identifier.isi | WOS:A1994PD27600019 | - |
| dc.identifier.issnl | 0022-328X | - |