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- Publisher Website: 10.1016/j.jorganchem.2007.11.031
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Article: Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)
| Title | Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II) |
|---|---|
| Authors | |
| Keywords | Phosphine Suzuki-Miyaura Coupling Palladium Pincer |
| Issue Date | 2008 |
| Citation | Journal of Organometallic Chemistry, 2008, v. 693, n. 8-9, p. 1628-1635 How to Cite? |
| Abstract | Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. © 2007 Elsevier B.V. All rights reserved. |
| Persistent Identifier | http://hdl.handle.net/10722/219565 |
| ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Neo, Kian Eang | - |
| dc.contributor.author | Huynh, Han Vinh | - |
| dc.contributor.author | Koh, Lip Lin | - |
| dc.contributor.author | Henderson, William | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:24Z | - |
| dc.date.available | 2015-09-23T02:57:24Z | - |
| dc.date.issued | 2008 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 2008, v. 693, n. 8-9, p. 1628-1635 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219565 | - |
| dc.description.abstract | Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. © 2007 Elsevier B.V. All rights reserved. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.subject | Phosphine | - |
| dc.subject | Suzuki-Miyaura Coupling | - |
| dc.subject | Palladium | - |
| dc.subject | Pincer | - |
| dc.title | Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/j.jorganchem.2007.11.031 | - |
| dc.identifier.scopus | eid_2-s2.0-41549117150 | - |
| dc.identifier.volume | 693 | - |
| dc.identifier.issue | 8-9 | - |
| dc.identifier.spage | 1628 | - |
| dc.identifier.epage | 1635 | - |
| dc.identifier.isi | WOS:000255891400030 | - |
| dc.identifier.issnl | 0022-328X | - |