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- Publisher Website: 10.1039/b713152f
- Scopus: eid_2-s2.0-38549124976
- PMID: 18217127
- WOS: WOS:000253046700019
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Article: Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions
Title | Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions |
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Authors | |
Issue Date | 2008 |
Citation | Dalton Transactions, 2008, n. 5, p. 699-706 How to Cite? |
Abstract | Novel Pd(ii) mixed N,S-heterocyclic carbene (NSHC)-phosphine complexes of the general formula [PdBr2(NSHC)(PR3)] were obtained from bridge cleavage of dinuclear NSHC complexes of type [PdBr2(NSHC)] 2 [NSHC = 3-benzylbenzothiazolin-2-ylidene and 3- propylbenzothiazolin-2-ylidene] with triphenylphosphine, tricyclohexylphosphine and 2-diphenylphosphanyl-pyridine. All complexes have been fully characterized by 1H and 13C NMR spectroscopy, ESI mass spectrometry and elemental analysis. The X-ray crystal structures of complexes 3-8 are reported. The complexes exhibit moderate to good catalytic activity in the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides. © The Royal Society of Chemistry 2008. |
Persistent Identifier | http://hdl.handle.net/10722/219562 |
ISSN | 2023 Impact Factor: 3.5 2023 SCImago Journal Rankings: 0.697 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Yen, Swee Kuan | - |
dc.contributor.author | Koh, Lip Lin | - |
dc.contributor.author | Huynh, Han Vinh | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:24Z | - |
dc.date.available | 2015-09-23T02:57:24Z | - |
dc.date.issued | 2008 | - |
dc.identifier.citation | Dalton Transactions, 2008, n. 5, p. 699-706 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219562 | - |
dc.description.abstract | Novel Pd(ii) mixed N,S-heterocyclic carbene (NSHC)-phosphine complexes of the general formula [PdBr2(NSHC)(PR3)] were obtained from bridge cleavage of dinuclear NSHC complexes of type [PdBr2(NSHC)] 2 [NSHC = 3-benzylbenzothiazolin-2-ylidene and 3- propylbenzothiazolin-2-ylidene] with triphenylphosphine, tricyclohexylphosphine and 2-diphenylphosphanyl-pyridine. All complexes have been fully characterized by 1H and 13C NMR spectroscopy, ESI mass spectrometry and elemental analysis. The X-ray crystal structures of complexes 3-8 are reported. The complexes exhibit moderate to good catalytic activity in the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides. © The Royal Society of Chemistry 2008. | - |
dc.language | eng | - |
dc.relation.ispartof | Dalton Transactions | - |
dc.title | Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/b713152f | - |
dc.identifier.pmid | 18217127 | - |
dc.identifier.scopus | eid_2-s2.0-38549124976 | - |
dc.identifier.issue | 5 | - |
dc.identifier.spage | 699 | - |
dc.identifier.epage | 706 | - |
dc.identifier.eissn | 1477-9234 | - |
dc.identifier.isi | WOS:000253046700019 | - |
dc.identifier.issnl | 1477-9226 | - |