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- Publisher Website: 10.1002/anie.200502532
- Scopus: eid_2-s2.0-28244483134
- PMID: 16252302
- WOS: WOS:000233694800010
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Article: Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel
| Title | Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel |
|---|---|
| Authors | |
| Keywords | Nickel Homogeneous catalysis Coordination modes Oligomerization N,P ligands |
| Issue Date | 2005 |
| Citation | Angewandte Chemie - International Edition, 2005, v. 44, n. 46, p. 7560-7564 How to Cite? |
| Abstract | (Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA. |
| Persistent Identifier | http://hdl.handle.net/10722/219499 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Weng, Zhiqiang | - |
| dc.contributor.author | Teo, Shihui | - |
| dc.contributor.author | Lip, Lin Koh | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:14Z | - |
| dc.date.available | 2015-09-23T02:57:14Z | - |
| dc.date.issued | 2005 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2005, v. 44, n. 46, p. 7560-7564 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219499 | - |
| dc.description.abstract | (Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | Nickel | - |
| dc.subject | Homogeneous catalysis | - |
| dc.subject | Coordination modes | - |
| dc.subject | Oligomerization | - |
| dc.subject | N,P ligands | - |
| dc.title | Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.200502532 | - |
| dc.identifier.pmid | 16252302 | - |
| dc.identifier.scopus | eid_2-s2.0-28244483134 | - |
| dc.identifier.volume | 44 | - |
| dc.identifier.issue | 46 | - |
| dc.identifier.spage | 7560 | - |
| dc.identifier.epage | 7564 | - |
| dc.identifier.isi | WOS:000233694800010 | - |
| dc.identifier.issnl | 1433-7851 | - |