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- Publisher Website: 10.1016/S0022-328X(00)98910-1
- Scopus: eid_2-s2.0-2742566561
- WOS: WOS:A1987K048700003
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Article: Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations
Title | Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations |
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Authors | |
Issue Date | 1987 |
Citation | Journal of Organometallic Chemistry, 1987, v. 331, n. 1, p. 23-28 How to Cite? |
Abstract | The ability of trimethylamine N-oxide as a chemical initiator for facile oxidative decarbonylation in metal carbonyls is manifested by the isolation of M(CO)3(η2-bipy)(η1-dppm) (where M Cr, Mo, W; bipy = 2,2′-bipyridyl; dppm = bis(diphenylphosphino)-methane). The synthetic strategy and spectral (IR and 1H and 31P NMR) characterisations are presented and discussed. Syntheses of the well-known M(CO)4(η2-bipy) have also been modified to give high yields at ambient temperature. © 1987. |
Persistent Identifier | http://hdl.handle.net/10722/219497 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Hor, T. S Andy | - |
dc.contributor.author | Chee, Sheh Mai | - |
dc.date.accessioned | 2015-09-23T02:57:14Z | - |
dc.date.available | 2015-09-23T02:57:14Z | - |
dc.date.issued | 1987 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 1987, v. 331, n. 1, p. 23-28 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10722/219497 | - |
dc.description.abstract | The ability of trimethylamine N-oxide as a chemical initiator for facile oxidative decarbonylation in metal carbonyls is manifested by the isolation of M(CO)3(η2-bipy)(η1-dppm) (where M Cr, Mo, W; bipy = 2,2′-bipyridyl; dppm = bis(diphenylphosphino)-methane). The synthetic strategy and spectral (IR and 1H and 31P NMR) characterisations are presented and discussed. Syntheses of the well-known M(CO)4(η2-bipy) have also been modified to give high yields at ambient temperature. © 1987. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organometallic Chemistry | - |
dc.title | Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0022-328X(00)98910-1 | - |
dc.identifier.scopus | eid_2-s2.0-2742566561 | - |
dc.identifier.volume | 331 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 23 | - |
dc.identifier.epage | 28 | - |
dc.identifier.isi | WOS:A1987K048700003 | - |
dc.identifier.issnl | 0022-328X | - |