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- Publisher Website: 10.1016/S0022-328X(98)00998-X
- Scopus: eid_2-s2.0-0005824832
- WOS: WOS:000079149100009
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Article: {M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography
| Title | {M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography |
|---|---|
| Authors | |
| Keywords | Sulfide Triangular X-ray single-crystal crystallography Aggregate Carbon monoxide Heterometallic Platinum |
| Issue Date | 1999 |
| Citation | Journal of Organometallic Chemistry, 1999, v. 575, n. 2, p. 223-231 How to Cite? |
| Abstract | Heterometallic addition of d8 complexes of Pd(II), Pt(II), Rh(I) and Ir(I) to Pt2(PPh3)4(μ-S)2 results in triangular aggregates [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) characterized by 31P-NMR spectroscopy and X-ray single-crystal crystallography. They show a trigonal bipyramidal {MPt2S2} core with three d8 sq-planar metal atoms aligned at close proximity but without direct M-M bonds. Unlike their d10 counterparts [Ag(I) and Cu(I)], these aggregates resist desulfurization under ambient pressure of CO. © 1999 Elsevier Science S.A. |
| Persistent Identifier | http://hdl.handle.net/10722/219403 |
| ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Li, Zhaohui | - |
| dc.contributor.author | Liu, Huang | - |
| dc.contributor.author | Mok, K. F. | - |
| dc.contributor.author | Batsanov, Andrei S. | - |
| dc.contributor.author | Howard, Judith A K | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:56:59Z | - |
| dc.date.available | 2015-09-23T02:56:59Z | - |
| dc.date.issued | 1999 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 1999, v. 575, n. 2, p. 223-231 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219403 | - |
| dc.description.abstract | Heterometallic addition of d8 complexes of Pd(II), Pt(II), Rh(I) and Ir(I) to Pt2(PPh3)4(μ-S)2 results in triangular aggregates [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) characterized by 31P-NMR spectroscopy and X-ray single-crystal crystallography. They show a trigonal bipyramidal {MPt2S2} core with three d8 sq-planar metal atoms aligned at close proximity but without direct M-M bonds. Unlike their d10 counterparts [Ag(I) and Cu(I)], these aggregates resist desulfurization under ambient pressure of CO. © 1999 Elsevier Science S.A. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.subject | Sulfide | - |
| dc.subject | Triangular | - |
| dc.subject | X-ray single-crystal crystallography | - |
| dc.subject | Aggregate | - |
| dc.subject | Carbon monoxide | - |
| dc.subject | Heterometallic | - |
| dc.subject | Platinum | - |
| dc.title | {M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/S0022-328X(98)00998-X | - |
| dc.identifier.scopus | eid_2-s2.0-0005824832 | - |
| dc.identifier.volume | 575 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | 223 | - |
| dc.identifier.epage | 231 | - |
| dc.identifier.isi | WOS:000079149100009 | - |
| dc.identifier.issnl | 0022-328X | - |