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- Publisher Website: 10.1039/b812644e
- Scopus: eid_2-s2.0-56849099606
- PMID: 19030624
- WOS: WOS:000261742700016
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Article: Self-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine)
Title | Self-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine) |
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Authors | |
Issue Date | 2008 |
Citation | Dalton Transactions, 2008, n. 46, p. 6619-6623 How to Cite? |
Abstract | The high reactivity of Group 10 metal-metal bonded complexes towards platinum chalcogenide compounds have been demonstrated through the successful isolation of a number of novel homo- and hetero-polynuclear complexes. A d 8-d9 pentanuclear sulfide cluster with a Pd3 triangle sandwiched by two Pt2 sheaths with peripheral protection from coordinated and pendant pyridyls has been isolated and characterized. Other related aggregates with the {Pt2M2X2} (X = S, Se) core have also been obtained from the addition of the [Pt2S 2] metalloligand to dinuclear Pd(I). © 2008 The Royal Society of Chemistry. |
Persistent Identifier | http://hdl.handle.net/10722/219370 |
ISSN | 2023 Impact Factor: 3.5 2023 SCImago Journal Rankings: 0.697 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Li, Jingqiu | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:56:54Z | - |
dc.date.available | 2015-09-23T02:56:54Z | - |
dc.date.issued | 2008 | - |
dc.identifier.citation | Dalton Transactions, 2008, n. 46, p. 6619-6623 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219370 | - |
dc.description.abstract | The high reactivity of Group 10 metal-metal bonded complexes towards platinum chalcogenide compounds have been demonstrated through the successful isolation of a number of novel homo- and hetero-polynuclear complexes. A d 8-d9 pentanuclear sulfide cluster with a Pd3 triangle sandwiched by two Pt2 sheaths with peripheral protection from coordinated and pendant pyridyls has been isolated and characterized. Other related aggregates with the {Pt2M2X2} (X = S, Se) core have also been obtained from the addition of the [Pt2S 2] metalloligand to dinuclear Pd(I). © 2008 The Royal Society of Chemistry. | - |
dc.language | eng | - |
dc.relation.ispartof | Dalton Transactions | - |
dc.title | Self-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine) | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/b812644e | - |
dc.identifier.pmid | 19030624 | - |
dc.identifier.scopus | eid_2-s2.0-56849099606 | - |
dc.identifier.issue | 46 | - |
dc.identifier.spage | 6619 | - |
dc.identifier.epage | 6623 | - |
dc.identifier.eissn | 1477-9234 | - |
dc.identifier.isi | WOS:000261742700016 | - |
dc.identifier.issnl | 1477-9226 | - |