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- Publisher Website: 10.1021/ic010905t
- Scopus: eid_2-s2.0-0037060802
- PMID: 11874355
- WOS: WOS:000174259300025
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Article: Metal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod)
| Title | Metal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod) |
|---|---|
| Authors | |
| Issue Date | 2002 |
| Citation | Inorganic Chemistry, 2002, v. 41, n. 5, p. 1194-1198 How to Cite? |
| Abstract | Pt2(μ-Se)2(PPh3)4 reacts with PtCl2(cod) to give {Pt2(μ3-Se)2(PPh3) 4[Pt(cod)]}2+ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ3-Se)2(PPh3)2[Pt(cod)] 2}2+. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected. |
| Persistent Identifier | http://hdl.handle.net/10722/219365 |
| ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Yeo, Jeremy S L | - |
| dc.contributor.author | Vittal, Jagadese J. | - |
| dc.contributor.author | Henderson, William | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:56:53Z | - |
| dc.date.available | 2015-09-23T02:56:53Z | - |
| dc.date.issued | 2002 | - |
| dc.identifier.citation | Inorganic Chemistry, 2002, v. 41, n. 5, p. 1194-1198 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219365 | - |
| dc.description.abstract | Pt2(μ-Se)2(PPh3)4 reacts with PtCl2(cod) to give {Pt2(μ3-Se)2(PPh3) 4[Pt(cod)]}2+ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ3-Se)2(PPh3)2[Pt(cod)] 2}2+. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganic Chemistry | - |
| dc.title | Metal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ic010905t | - |
| dc.identifier.pmid | 11874355 | - |
| dc.identifier.scopus | eid_2-s2.0-0037060802 | - |
| dc.identifier.volume | 41 | - |
| dc.identifier.issue | 5 | - |
| dc.identifier.spage | 1194 | - |
| dc.identifier.epage | 1198 | - |
| dc.identifier.isi | WOS:000174259300025 | - |
| dc.identifier.issnl | 0020-1669 | - |