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- Publisher Website: 10.1016/0022-328X(89)85061-2
- Scopus: eid_2-s2.0-0000210784
- WOS: WOS:A1989AP99900005
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Article: Substituted metal carbonyls XI. 1,1′-Bis(diphenylphosphino)ferrocene - a bridging, chelating and unidentate ligand in the synthesis of M2(CO)10(μ-PP), M(CO)4(η2-PP) and M(CO)5(η1-PP) (where M = Cr, Mo, W and PP = Fe(C5H4PPh2)2)
| Title | Substituted metal carbonyls XI. 1,1′-Bis(diphenylphosphino)ferrocene - a bridging, chelating and unidentate ligand in the synthesis of M2(CO)10(μ-PP), M(CO)4(η2-PP) and M(CO)5(η1-PP) (where M = Cr, Mo, W and PP = Fe(C5H4PPh2)2) |
|---|---|
| Authors | |
| Issue Date | 1989 |
| Citation | Journal of Organometallic Chemistry, 1989, v. 373, n. 3, p. 319-324 How to Cite? |
| Abstract | Trimethylamine N-oxide-initiated decarbonylation of M(CO)6 (M = Cr, Mo, W) followed by nucleophilic attack by 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords a mixture of heterometallic products which consists mainly of a chelate with a bidentate diphosphine, M(CO)4(dppf), and a dinuclear phosphine-bridged complex M2(CO)10(dppf) at ambient temperature (28° C). The corresponding unidentate diphosphine, M(CO)5(dppf), is obtained as the major isolable product at 10° C. The IR and NMR (1H and 31P) spectral data and the structural properties of these complexes are presented and discussed. © 1989. |
| Persistent Identifier | http://hdl.handle.net/10722/219347 |
| ISSN | 2021 Impact Factor: 2.345 2020 SCImago Journal Rankings: 0.484 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Hor, T. S Andy | - |
| dc.contributor.author | Phang, Lai Tee | - |
| dc.date.accessioned | 2015-09-23T02:56:51Z | - |
| dc.date.available | 2015-09-23T02:56:51Z | - |
| dc.date.issued | 1989 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 1989, v. 373, n. 3, p. 319-324 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219347 | - |
| dc.description.abstract | Trimethylamine N-oxide-initiated decarbonylation of M(CO)6 (M = Cr, Mo, W) followed by nucleophilic attack by 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords a mixture of heterometallic products which consists mainly of a chelate with a bidentate diphosphine, M(CO)4(dppf), and a dinuclear phosphine-bridged complex M2(CO)10(dppf) at ambient temperature (28° C). The corresponding unidentate diphosphine, M(CO)5(dppf), is obtained as the major isolable product at 10° C. The IR and NMR (1H and 31P) spectral data and the structural properties of these complexes are presented and discussed. © 1989. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.title | Substituted metal carbonyls XI. 1,1′-Bis(diphenylphosphino)ferrocene - a bridging, chelating and unidentate ligand in the synthesis of M2(CO)10(μ-PP), M(CO)4(η2-PP) and M(CO)5(η1-PP) (where M = Cr, Mo, W and PP = Fe(C5H4PPh2)2) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/0022-328X(89)85061-2 | - |
| dc.identifier.scopus | eid_2-s2.0-0000210784 | - |
| dc.identifier.volume | 373 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.spage | 319 | - |
| dc.identifier.epage | 324 | - |
| dc.identifier.isi | WOS:A1989AP99900005 | - |
| dc.identifier.issnl | 0022-328X | - |