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- Publisher Website: 10.1515/pac-2014-0709
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Article: Reengineering Classic Organic Reactions Using Polymeric Tools
Title | Reengineering Classic Organic Reactions Using Polymeric Tools |
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Authors | |
Keywords | Appel reactions Mitsunobu reactions Mizoroki-Heck reactions POC-2014 Polymer-supported catalysts Polymer-supported reagents Suzuki-Miyaura reactions Wittig reactions |
Issue Date | 2014 |
Publisher | Walter de Gruyter GmbH. The Journal's web site is located at http://www.degruyter.com/view/j/pac |
Citation | Pure and Applied Chemistry, 2014, v. 86 n. 11, p. 1651-1661 How to Cite? |
Abstract | Many of the most widely used reactions in organic synthesis suffer from drawbacks that can hamper their use. For example, the Mitsunobu, Wittig and Appel reactions all result in the formation of a full equivalent of triphenylphosphine oxide, which can be similar in polarity to the desired product, and thus be difficult to remove. Other reactions such as the Suzuki-Miyaura and Mizoroki-Heck reactions require the addition of numerous reagents, ligands and catalysts that can be laborious to separate from the targeted cross-coupled product. This review summarizes our recent work to address these issues by developing polymeric tools designed to simplify product isolation from these transformations. |
Description | Paper based on presentation at the 15th International Conference on Polymers and Organic Chemistry (POC-2014), Timisoara, Romania, 10–13 June 2014 |
Persistent Identifier | http://hdl.handle.net/10722/215156 |
ISSN | 2023 Impact Factor: 2.0 2023 SCImago Journal Rankings: 0.435 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Toy, PH | - |
dc.date.accessioned | 2015-08-21T13:16:23Z | - |
dc.date.available | 2015-08-21T13:16:23Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | Pure and Applied Chemistry, 2014, v. 86 n. 11, p. 1651-1661 | - |
dc.identifier.issn | 0033-4545 | - |
dc.identifier.uri | http://hdl.handle.net/10722/215156 | - |
dc.description | Paper based on presentation at the 15th International Conference on Polymers and Organic Chemistry (POC-2014), Timisoara, Romania, 10–13 June 2014 | - |
dc.description.abstract | Many of the most widely used reactions in organic synthesis suffer from drawbacks that can hamper their use. For example, the Mitsunobu, Wittig and Appel reactions all result in the formation of a full equivalent of triphenylphosphine oxide, which can be similar in polarity to the desired product, and thus be difficult to remove. Other reactions such as the Suzuki-Miyaura and Mizoroki-Heck reactions require the addition of numerous reagents, ligands and catalysts that can be laborious to separate from the targeted cross-coupled product. This review summarizes our recent work to address these issues by developing polymeric tools designed to simplify product isolation from these transformations. | - |
dc.language | eng | - |
dc.publisher | Walter de Gruyter GmbH. The Journal's web site is located at http://www.degruyter.com/view/j/pac | - |
dc.relation.ispartof | Pure and Applied Chemistry | - |
dc.rights | © 2014 IUPAC & De Gruyter. The final publication is available at www.degruyter.com | - |
dc.subject | Appel reactions | - |
dc.subject | Mitsunobu reactions | - |
dc.subject | Mizoroki-Heck reactions | - |
dc.subject | POC-2014 | - |
dc.subject | Polymer-supported catalysts | - |
dc.subject | Polymer-supported reagents | - |
dc.subject | Suzuki-Miyaura reactions | - |
dc.subject | Wittig reactions | - |
dc.title | Reengineering Classic Organic Reactions Using Polymeric Tools | - |
dc.type | Article | - |
dc.identifier.email | Toy, PH: phtoy@hkucc.hku.hk | - |
dc.identifier.authority | Toy, PH=rp00791 | - |
dc.description.nature | published_or_final_version | - |
dc.identifier.doi | 10.1515/pac-2014-0709 | - |
dc.identifier.scopus | eid_2-s2.0-84924057221 | - |
dc.identifier.hkuros | 247802 | - |
dc.identifier.volume | 86 | - |
dc.identifier.issue | 11 | - |
dc.identifier.spage | 1651 | - |
dc.identifier.epage | 1661 | - |
dc.identifier.isi | WOS:000345063300004 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 0033-4545 | - |