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Article: Alkenyl/Thiol-Derived Metal-Organic Frameworks (MOFs) by Means of Postsynthetic Modification for Effective Mercury Adsorption

TitleAlkenyl/Thiol-Derived Metal-Organic Frameworks (MOFs) by Means of Postsynthetic Modification for Effective Mercury Adsorption
Authors
Liu, TChe, JXHu, YZDong, XWLiu, XYChe, CM
Keywordsadsorption
carbon
mercury
metal-organic frameworks
postsynthetic modification
Issue Date2014
PublisherWiley.
Citation
Chemistry - A European Journal, 2014, v. 20, p. 14090-14095 How to Cite?
DOI: http://dx.doi.org/10.1002/chem.201403382
AbstractThe synthesis of new functionally diverse alkenyl-derived Cr-MIL-101s (MIL=material of Institute Lavoisier) was realized by a novel and convenient postsynthetic modification (PSM) protocol by means of the carbon[BOND]carbon bond-forming Mizoroki–Heck reaction. The new PSM protocol demonstrates a broad scope of substrates with excellent tolerance of functionality under mild reaction conditions. Moreover, a new metal–organic framework (MOF) that bears both alkenyl and thiol side chains prepared by means of the tandem PSM method has shown excellent adsorbent ability in removing mercury ions from water.
Persistent Identifierhttp://hdl.handle.net/10722/215134
ISI Accession Number ID
WOS:000343800700038

 

DC FieldValueLanguage
dc.contributor.authorLiu, T-
dc.contributor.authorChe, JX-
dc.contributor.authorHu, YZ-
dc.contributor.authorDong, XW-
dc.contributor.authorLiu, XY-
dc.contributor.authorChe, CM-
dc.date.accessioned2015-08-21T13:15:23Z-
dc.date.available2015-08-21T13:15:23Z-
dc.date.issued2014-
dc.identifier.citationChemistry - A European Journal, 2014, v. 20, p. 14090-14095-
dc.identifier.urihttp://hdl.handle.net/10722/215134-
dc.description.abstractThe synthesis of new functionally diverse alkenyl-derived Cr-MIL-101s (MIL=material of Institute Lavoisier) was realized by a novel and convenient postsynthetic modification (PSM) protocol by means of the carbon[BOND]carbon bond-forming Mizoroki–Heck reaction. The new PSM protocol demonstrates a broad scope of substrates with excellent tolerance of functionality under mild reaction conditions. Moreover, a new metal–organic framework (MOF) that bears both alkenyl and thiol side chains prepared by means of the tandem PSM method has shown excellent adsorbent ability in removing mercury ions from water.-
dc.languageeng-
dc.publisherWiley. -
dc.relation.ispartofChemistry - A European Journal-
dc.rightsPreprint This is the pre-peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article]. Authors are not required to remove preprints posted prior to acceptance of the submitted version. Postprint This is the accepted version of the following article: [full citation], which has been published in final form at [Link to final article]. In addition, authors may also transmit, print and share copies with colleagues, provided that there is no systematic distribution of the submitted version, e.g. posting on a listserve, network or automated delivery. -
dc.subjectadsorption-
dc.subjectcarbon-
dc.subjectmercury-
dc.subjectmetal-organic frameworks-
dc.subjectpostsynthetic modification-
dc.titleAlkenyl/Thiol-Derived Metal-Organic Frameworks (MOFs) by Means of Postsynthetic Modification for Effective Mercury Adsorption-
dc.typeArticle-
dc.identifier.emailChe, CM: cmche@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.identifier.doi10.1002/chem.201403382-
dc.identifier.scopuseid_2-s2.0-84941040808-
dc.identifier.hkuros246898-
dc.identifier.volume20-
dc.identifier.spage14090-
dc.identifier.epage14095-
dc.identifier.isiWOS:000343800700038-
dc.publisher.placeWeinheim, Germany-

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