File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1016/j.tetlet.2010.06.066
- Scopus: eid_2-s2.0-77957112412
- WOS: WOS:000283385900005
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Significant counterion effect of the In(III)-pybox complex in highly enantioselective carbonyl-ene reactions of ethyl glyoxylate
Title | Significant counterion effect of the In(III)-pybox complex in highly enantioselective carbonyl-ene reactions of ethyl glyoxylate |
---|---|
Authors | |
Issue Date | 2010 |
Publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet |
Citation | Tetrahedron Letters, 2010, v. 51 n. 43, p. 5649-5652 How to Cite? |
Abstract | A highly efficient enantioselective carbonyl-ene reaction of ethyl glyoxylate catalyzed by an In(III)-pybox complex, which is designed based on the counterion effect, is reported. Reactions of both aliphatic and aromatic 1,1-disubstituted olefins proceed smoothly to give enantioenriched homoallylic alcohols with excellent yields and enantioselectivities. In addition, electron-withdrawing as well as donating groups on the phenyl ring of α-methyl styrenes are tolerated in this reaction. © 2010 Elsevier Ltd. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/182340 |
ISSN | 2023 Impact Factor: 1.5 2023 SCImago Journal Rankings: 0.323 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhao, JF | en_US |
dc.contributor.author | Tjan, TBW | en_US |
dc.contributor.author | Loh, TP | en_US |
dc.date.accessioned | 2013-04-23T08:19:01Z | - |
dc.date.available | 2013-04-23T08:19:01Z | - |
dc.date.issued | 2010 | en_US |
dc.identifier.citation | Tetrahedron Letters, 2010, v. 51 n. 43, p. 5649-5652 | en_US |
dc.identifier.issn | 0040-4039 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/182340 | - |
dc.description.abstract | A highly efficient enantioselective carbonyl-ene reaction of ethyl glyoxylate catalyzed by an In(III)-pybox complex, which is designed based on the counterion effect, is reported. Reactions of both aliphatic and aromatic 1,1-disubstituted olefins proceed smoothly to give enantioenriched homoallylic alcohols with excellent yields and enantioselectivities. In addition, electron-withdrawing as well as donating groups on the phenyl ring of α-methyl styrenes are tolerated in this reaction. © 2010 Elsevier Ltd. All rights reserved. | en_US |
dc.language | eng | en_US |
dc.publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet | en_US |
dc.relation.ispartof | Tetrahedron Letters | en_US |
dc.title | Significant counterion effect of the In(III)-pybox complex in highly enantioselective carbonyl-ene reactions of ethyl glyoxylate | en_US |
dc.type | Article | en_US |
dc.identifier.email | Zhao, JF: zhao0065@e.ntu.edu.sg | en_US |
dc.identifier.authority | Zhao, JF=rp01745 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/j.tetlet.2010.06.066 | en_US |
dc.identifier.scopus | eid_2-s2.0-77957112412 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-77957112412&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 51 | en_US |
dc.identifier.issue | 43 | en_US |
dc.identifier.spage | 5649 | en_US |
dc.identifier.epage | 5652 | en_US |
dc.identifier.isi | WOS:000283385900005 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Zhao, JF=8393022100 | en_US |
dc.identifier.scopusauthorid | Tjan, TBW=35243601000 | en_US |
dc.identifier.scopusauthorid | Loh, TP=35234192600 | en_US |
dc.identifier.issnl | 0040-4039 | - |