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- Publisher Website: 10.1021/ol902507x
- Scopus: eid_2-s2.0-72849122521
- PMID: 19911807
- WOS: WOS:000272461800037
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Article: Highly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complex
Title | Highly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complex |
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Authors | |
Issue Date | 2009 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html |
Citation | Organic Letters, 2009, v. 11 n. 24, p. 5714-5716 How to Cite? |
Abstract | [Chemical Equation Presented] A chiral indium(III)-pybox complex catalyzed asymmetric ketone-ene reaction of trifluoropyruvate is described. Both aromatic and aliphatic 1,1-disubstituted alkenes reacted smoothly to give the enantioenriched tertiary homoallylic alcohols in good to excellent yields (up to 99%) and with excellent enantioselectivities (up to 98% ee). © 2009 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/182337 |
ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhao, JF | en_US |
dc.contributor.author | Tjan, TBW | en_US |
dc.contributor.author | Tan, BH | en_US |
dc.contributor.author | Loh, TP | en_US |
dc.date.accessioned | 2013-04-23T08:19:00Z | - |
dc.date.available | 2013-04-23T08:19:00Z | - |
dc.date.issued | 2009 | en_US |
dc.identifier.citation | Organic Letters, 2009, v. 11 n. 24, p. 5714-5716 | en_US |
dc.identifier.issn | 1523-7060 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/182337 | - |
dc.description.abstract | [Chemical Equation Presented] A chiral indium(III)-pybox complex catalyzed asymmetric ketone-ene reaction of trifluoropyruvate is described. Both aromatic and aliphatic 1,1-disubstituted alkenes reacted smoothly to give the enantioenriched tertiary homoallylic alcohols in good to excellent yields (up to 99%) and with excellent enantioselectivities (up to 98% ee). © 2009 American Chemical Society. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html | en_US |
dc.relation.ispartof | Organic Letters | en_US |
dc.title | Highly enantioselective ketone-ene reactions of trifluoropyruvate: Significant counterion effect of the in(III)-pybox complex | en_US |
dc.type | Article | en_US |
dc.identifier.email | Zhao, JF: zhao0065@e.ntu.edu.sg | en_US |
dc.identifier.authority | Zhao, JF=rp01745 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ol902507x | en_US |
dc.identifier.pmid | 19911807 | - |
dc.identifier.scopus | eid_2-s2.0-72849122521 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-72849122521&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 11 | en_US |
dc.identifier.issue | 24 | en_US |
dc.identifier.spage | 5714 | en_US |
dc.identifier.epage | 5716 | en_US |
dc.identifier.isi | WOS:000272461800037 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Zhao, JF=8393022100 | en_US |
dc.identifier.scopusauthorid | Tjan, TBW=35243601000 | en_US |
dc.identifier.scopusauthorid | Tan, BH=35244029100 | en_US |
dc.identifier.scopusauthorid | Loh, TP=35234192600 | en_US |
dc.identifier.issnl | 1523-7052 | - |