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Conference Paper: Development and validation of analytical methodology using capillary electrophoresis for separation and determination of anions in rainwater

TitleDevelopment and validation of analytical methodology using capillary electrophoresis for separation and determination of anions in rainwater
Authors
KeywordsAcid Rain
Anion Analysis
Capillary Electrophoresis
Organic Anion Analysis
Trace Analysis
Issue Date1998
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/talanta
Citation
Talanta, 1998, v. 45 n. 4, p. 641-656 How to Cite?
AbstractA new capillary electrophoresis (CE) procedure was developed for simultaneous determination of both organic and inorganic anions in rain water using a background electrolyte (BGE) containing 5 mM molybdate, 0.15 mM CTAH, 0.01% PVA and 5 mM Tris buffer to adjust pH at 7.9. Under optimised conditions, good repeatability (RSD for sulphate in migration time = 0.36% and peak area = 4.2%), low detection limit (2 ppb for chloride) and satisfactory working range (50 ppb - 20 ppm for hydrodynamic injection, 10 ppb 3 ppm for electrokinetic injection for chloride) were obtained. The reliability of the CE procedure developed was established by satisfactory recovery tests and good agreement of results obtained by both the CE and ion chromatography (IC) methods. The procedure developed had been successfully applied for field monitoring of rainwater showing good repeatability and capability of detecting trace anions at ppb levels beyond the IC working range. Thus, the new CE procedure developed provides a quick, sensitive, economic and reliable method to meet the need for the simultaneous determination of both organic and inorganic anions in the acid rain monitoring programme.
Persistent Identifierhttp://hdl.handle.net/10722/168801
ISSN
2023 Impact Factor: 5.6
2023 SCImago Journal Rankings: 0.956
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorFung, YSen_US
dc.contributor.authorLau, KMen_US
dc.date.accessioned2012-10-08T03:34:24Z-
dc.date.available2012-10-08T03:34:24Z-
dc.date.issued1998en_US
dc.identifier.citationTalanta, 1998, v. 45 n. 4, p. 641-656en_US
dc.identifier.issn0039-9140en_US
dc.identifier.urihttp://hdl.handle.net/10722/168801-
dc.description.abstractA new capillary electrophoresis (CE) procedure was developed for simultaneous determination of both organic and inorganic anions in rain water using a background electrolyte (BGE) containing 5 mM molybdate, 0.15 mM CTAH, 0.01% PVA and 5 mM Tris buffer to adjust pH at 7.9. Under optimised conditions, good repeatability (RSD for sulphate in migration time = 0.36% and peak area = 4.2%), low detection limit (2 ppb for chloride) and satisfactory working range (50 ppb - 20 ppm for hydrodynamic injection, 10 ppb 3 ppm for electrokinetic injection for chloride) were obtained. The reliability of the CE procedure developed was established by satisfactory recovery tests and good agreement of results obtained by both the CE and ion chromatography (IC) methods. The procedure developed had been successfully applied for field monitoring of rainwater showing good repeatability and capability of detecting trace anions at ppb levels beyond the IC working range. Thus, the new CE procedure developed provides a quick, sensitive, economic and reliable method to meet the need for the simultaneous determination of both organic and inorganic anions in the acid rain monitoring programme.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/talantaen_US
dc.relation.ispartofTalantaen_US
dc.subjectAcid Rainen_US
dc.subjectAnion Analysisen_US
dc.subjectCapillary Electrophoresisen_US
dc.subjectOrganic Anion Analysisen_US
dc.subjectTrace Analysisen_US
dc.titleDevelopment and validation of analytical methodology using capillary electrophoresis for separation and determination of anions in rainwateren_US
dc.typeConference_Paperen_US
dc.identifier.emailFung, YS:ysfung@hku.hken_US
dc.identifier.authorityFung, YS=rp00697en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0039-9140(97)00284-1en_US
dc.identifier.pmid18967046-
dc.identifier.scopuseid_2-s2.0-0032004974en_US
dc.identifier.hkuros31422-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0032004974&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume45en_US
dc.identifier.issue4en_US
dc.identifier.spage641en_US
dc.identifier.epage656en_US
dc.identifier.isiWOS:000072165000006-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridFung, YS=13309754700en_US
dc.identifier.scopusauthoridLau, KM=7401559826en_US
dc.identifier.issnl0039-9140-

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