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- Publisher Website: 10.1039/c2cc30441d
- Scopus: eid_2-s2.0-84859587639
- PMID: 22447038
- WOS: WOS:000302363400007
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Article: Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand
Title | Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand |
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Authors | |
Issue Date | 2012 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
Citation | Chemical Communications, 2012, v. 48 n. 36, p. 4299-4301 How to Cite? |
Abstract | The chiral iridium porphyrin [Ir((-)-D 4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee). © The Royal Society of Chemistry 2012. |
Persistent Identifier | http://hdl.handle.net/10722/168620 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 1.133 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Wang, JC | en_US |
dc.contributor.author | Xu, ZJ | en_US |
dc.contributor.author | Guo, Z | en_US |
dc.contributor.author | Deng, QH | en_US |
dc.contributor.author | Zhou, CY | en_US |
dc.contributor.author | Wan, XL | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:21:41Z | - |
dc.date.available | 2012-10-08T03:21:41Z | - |
dc.date.issued | 2012 | en_US |
dc.identifier.citation | Chemical Communications, 2012, v. 48 n. 36, p. 4299-4301 | en_US |
dc.identifier.issn | 1359-7345 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168620 | - |
dc.description.abstract | The chiral iridium porphyrin [Ir((-)-D 4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee). © The Royal Society of Chemistry 2012. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | en_US |
dc.relation.ispartof | Chemical Communications | en_US |
dc.subject.mesh | Carbon - chemistry | - |
dc.subject.mesh | Hydrogen - chemistry | - |
dc.subject.mesh | Iridium - chemistry | - |
dc.subject.mesh | Metalloporphyrins - chemistry | - |
dc.subject.mesh | Methane - analogs and derivatives - chemistry | - |
dc.title | Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand | en_US |
dc.type | Article | en_US |
dc.identifier.email | Zhou, CY:cyzhou@hku.hk | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Zhou, CY=rp00843 | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/c2cc30441d | en_US |
dc.identifier.pmid | 22447038 | - |
dc.identifier.scopus | eid_2-s2.0-84859587639 | en_US |
dc.identifier.hkuros | 204518 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-84859587639&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 48 | en_US |
dc.identifier.issue | 36 | en_US |
dc.identifier.spage | 4299 | en_US |
dc.identifier.epage | 4301 | en_US |
dc.identifier.isi | WOS:000302363400007 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Wang, JC=52464857400 | en_US |
dc.identifier.scopusauthorid | Xu, ZJ=8708548900 | en_US |
dc.identifier.scopusauthorid | Guo, Z=36554069300 | en_US |
dc.identifier.scopusauthorid | Deng, QH=8987982900 | en_US |
dc.identifier.scopusauthorid | Zhou, CY=35742480200 | en_US |
dc.identifier.scopusauthorid | Wan, XL=55180731300 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 1359-7345 | - |