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Article: Mechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis

TitleMechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis
Authors
Cividino, PDheuAndries, MLOu, JMilet, APy, SToy, PH
KeywordsImines
Iminosugars
Mp2 Calculations
Nitrone Deoxygenation
Phosphines
Issue Date2009
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet
Citation
Tetrahedron Letters, 2009, v. 50 n. 50, p. 7038-7042 How to Cite?
DOI: http://dx.doi.org/10.1016/j.tetlet.2009.09.175
AbstractCarbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones. © 2009 Elsevier Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/168413
ISSN
0040-4039
2023 Impact Factor: 1.5
2023 SCImago Journal Rankings: 0.323
ISI Accession Number ID
WOS:000271841900029
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorCividino, Pen_US
dc.contributor.authorDheuAndries, MLen_US
dc.contributor.authorOu, Jen_US
dc.contributor.authorMilet, Aen_US
dc.contributor.authorPy, Sen_US
dc.contributor.authorToy, PHen_US
dc.date.accessioned2012-10-08T03:18:39Z-
dc.date.available2012-10-08T03:18:39Z-
dc.date.issued2009en_US
dc.identifier.citationTetrahedron Letters, 2009, v. 50 n. 50, p. 7038-7042en_US
dc.identifier.issn0040-4039en_US
dc.identifier.urihttp://hdl.handle.net/10722/168413-
dc.description.abstractCarbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones. © 2009 Elsevier Ltd. All rights reserved.en_US
dc.languageengen_US
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetleten_US
dc.relation.ispartofTetrahedron Lettersen_US
dc.subjectIminesen_US
dc.subjectIminosugarsen_US
dc.subjectMp2 Calculationsen_US
dc.subjectNitrone Deoxygenationen_US
dc.subjectPhosphinesen_US
dc.titleMechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesisen_US
dc.typeArticleen_US
dc.identifier.emailToy, PH:phtoy@hkucc.hku.hken_US
dc.identifier.authorityToy, PH=rp00791en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/j.tetlet.2009.09.175en_US
dc.identifier.scopuseid_2-s2.0-70350754541en_US
dc.identifier.hkuros170478-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-70350754541&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume50en_US
dc.identifier.issue50en_US
dc.identifier.spage7038en_US
dc.identifier.epage7042en_US
dc.identifier.isiWOS:000271841900029-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridCividino, P=7801585572en_US
dc.identifier.scopusauthoridDheuAndries, ML=6504154520en_US
dc.identifier.scopusauthoridOu, J=35234687200en_US
dc.identifier.scopusauthoridMilet, A=6701366879en_US
dc.identifier.scopusauthoridPy, S=6602523031en_US
dc.identifier.scopusauthoridToy, PH=7006579247en_US
dc.identifier.citeulike5913446-
dc.identifier.issnl0040-4039-

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