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Article: On the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydrides

TitleOn the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydrides
Authors
Li, XYuan, YBerkowitz, WFTodaro, LJDanishefsky, SJ
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2008, v. 130 n. 40, p. 13222-13224 How to Cite?
DOI: http://dx.doi.org/10.1021/ja8047078
AbstractMicrowave induced two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate mixed anhydride (FCMA) is proposed as the reactive intermediate, which undergoes 1,3-O→N acyl transfer to give the observed product. The formation and survival of the labile FCMA system has been evaluated. Copyright © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168328
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID
WOS:000259675500018
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorLi, Xen_US
dc.contributor.authorYuan, Yen_US
dc.contributor.authorBerkowitz, WFen_US
dc.contributor.authorTodaro, LJen_US
dc.contributor.authorDanishefsky, SJen_US
dc.date.accessioned2012-10-08T03:17:39Z-
dc.date.available2012-10-08T03:17:39Z-
dc.date.issued2008en_US
dc.identifier.citationJournal Of The American Chemical Society, 2008, v. 130 n. 40, p. 13222-13224en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10722/168328-
dc.description.abstractMicrowave induced two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate mixed anhydride (FCMA) is proposed as the reactive intermediate, which undergoes 1,3-O→N acyl transfer to give the observed product. The formation and survival of the labile FCMA system has been evaluated. Copyright © 2008 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_US
dc.relation.ispartofJournal of the American Chemical Societyen_US
dc.subject.meshAmides - Chemistryen_US
dc.subject.meshAnhydrides - Chemistryen_US
dc.subject.meshCarboxylic Acids - Chemistryen_US
dc.subject.meshFormic Acids - Chemistryen_US
dc.subject.meshMicrowavesen_US
dc.subject.meshModels, Molecularen_US
dc.subject.meshMolecular Structureen_US
dc.subject.meshNitriles - Chemistryen_US
dc.titleOn the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydridesen_US
dc.typeArticleen_US
dc.identifier.emailLi, X:xuechenl@hku.hken_US
dc.identifier.authorityLi, X=rp00742en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ja8047078en_US
dc.identifier.pmid18783224-
dc.identifier.scopuseid_2-s2.0-53549108902en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-53549108902&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume130en_US
dc.identifier.issue40en_US
dc.identifier.spage13222en_US
dc.identifier.epage13224en_US
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000259675500018-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridLi, X=24168958800en_US
dc.identifier.scopusauthoridYuan, Y=35180688100en_US
dc.identifier.scopusauthoridBerkowitz, WF=55275603600en_US
dc.identifier.scopusauthoridTodaro, LJ=7004233791en_US
dc.identifier.scopusauthoridDanishefsky, SJ=7202925243en_US
dc.identifier.issnl0002-7863-

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