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Article: Kinetics of electron transfer between metal hexacyanide complexes

TitleKinetics of electron transfer between metal hexacyanide complexes
Authors
Cho, KCCham, PMChe, CM
Issue Date1990
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1990, v. 168 n. 3-4, p. 361-364 How to Cite?
DOI: http://dx.doi.org/10.1016/0009-2614(90)85625-M
AbstractThe electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990.
Persistent Identifierhttp://hdl.handle.net/10722/168293
ISSN
0009-2614
2023 Impact Factor: 2.8
2023 SCImago Journal Rankings: 0.502
ISI Accession Number ID
WOS:A1990DE08800024

 

DC FieldValueLanguage
dc.contributor.authorCho, KCen_US
dc.contributor.authorCham, PMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:17:09Z-
dc.date.available2012-10-08T03:17:09Z-
dc.date.issued1990en_US
dc.identifier.citationChemical Physics Letters, 1990, v. 168 n. 3-4, p. 361-364en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/168293-
dc.description.abstractThe electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleKinetics of electron transfer between metal hexacyanide complexesen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0009-2614(90)85625-M-
dc.identifier.scopuseid_2-s2.0-4243338601en_US
dc.identifier.volume168en_US
dc.identifier.issue3-4en_US
dc.identifier.spage361en_US
dc.identifier.epage364en_US
dc.identifier.isiWOS:A1990DE08800024-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridCho, KC=15129672200en_US
dc.identifier.scopusauthoridCham, PM=36964387800en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.issnl0009-2614-

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