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Article: Structural and mechanistic studies of co-ordination compounds. Part 25. Synthesis and characterization of some octahedral halogeno-amine and -thioether complexes of ruthenium-(II) and -(III)
Title | Structural and mechanistic studies of co-ordination compounds. Part 25. Synthesis and characterization of some octahedral halogeno-amine and -thioether complexes of ruthenium-(II) and -(III) |
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Authors | |
Issue Date | 1980 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society, Dalton Transactions, 1980 n. 5, p. 756-762 How to Cite? |
Abstract | The published methods for the syntheses of trans-[RuLCl2]+ [L = L1, bis(ethane-1,2-diamine); L4, 3,7-diazanonane-1,9-diamine; or L7, 1,4,8,11-tetra-azacyclotetradecane] have been modified. The modified method is highly efficient and reproducible and it has been employed to prepare other trans-[RuLCl2]+ complexes [L = L2, bis(propane-1,3-diamine); L3, bis(NN′-dimethylethane-1,2-diamine); L5, 4,7-diazadecane-1,10-diamine; or L6, 4,8-diazaundecane-1,11-diamine]. Other dihalogeno-complexes, trans-[RuLBr2]+ (L = L1, L2, L4, or L7) and trans-[RuLI2]+ (L = L1 or L4), have been prepared form their corresponding dichloro-complexes through the reactive ruthenium(II) intermediates. Mixed halogeno-complexes of the type trans-[RuL1(X)Y]+ [(X)Y = (Cl) Br, (Cl)l, or (l)Br] have been prepared by metathetical procedures. Meanwhile, some macrocyclic quadridentate thioether complexes trans-[RuLCl2]·2H2O (L = L8, 1,4,8,11-tetrathiacyclotetradecane; or L9, 3,6,10,13-tetrathiabicyclo[13.4.0]nona-1,16,18-triene) and trans-[RuL8Cl2][ClO4]·H2O have also been synthesized. All these complexes are low-spin monomeric species. The electronic and i.r. absorption spectra of these complexes are discussed. |
Persistent Identifier | http://hdl.handle.net/10722/168261 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Poon, CK | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:16:47Z | - |
dc.date.available | 2012-10-08T03:16:47Z | - |
dc.date.issued | 1980 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 1980 n. 5, p. 756-762 | en_US |
dc.identifier.issn | 1472-7773 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168261 | - |
dc.description.abstract | The published methods for the syntheses of trans-[RuLCl2]+ [L = L1, bis(ethane-1,2-diamine); L4, 3,7-diazanonane-1,9-diamine; or L7, 1,4,8,11-tetra-azacyclotetradecane] have been modified. The modified method is highly efficient and reproducible and it has been employed to prepare other trans-[RuLCl2]+ complexes [L = L2, bis(propane-1,3-diamine); L3, bis(NN′-dimethylethane-1,2-diamine); L5, 4,7-diazadecane-1,10-diamine; or L6, 4,8-diazaundecane-1,11-diamine]. Other dihalogeno-complexes, trans-[RuLBr2]+ (L = L1, L2, L4, or L7) and trans-[RuLI2]+ (L = L1 or L4), have been prepared form their corresponding dichloro-complexes through the reactive ruthenium(II) intermediates. Mixed halogeno-complexes of the type trans-[RuL1(X)Y]+ [(X)Y = (Cl) Br, (Cl)l, or (l)Br] have been prepared by metathetical procedures. Meanwhile, some macrocyclic quadridentate thioether complexes trans-[RuLCl2]·2H2O (L = L8, 1,4,8,11-tetrathiacyclotetradecane; or L9, 3,6,10,13-tetrathiabicyclo[13.4.0]nona-1,16,18-triene) and trans-[RuL8Cl2][ClO4]·H2O have also been synthesized. All these complexes are low-spin monomeric species. The electronic and i.r. absorption spectra of these complexes are discussed. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Structural and mechanistic studies of co-ordination compounds. Part 25. Synthesis and characterization of some octahedral halogeno-amine and -thioether complexes of ruthenium-(II) and -(III) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9800000756 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049100246 | en_US |
dc.identifier.issue | 5 | en_US |
dc.identifier.spage | 756 | en_US |
dc.identifier.epage | 762 | en_US |
dc.identifier.isi | WOS:A1980JS44600011 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Poon, CK=7202673504 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 1364-5447 | - |