File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1039/DT9810001336
- Scopus: eid_2-s2.0-37049094034
- WOS: WOS:A1981LU63500018
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Structural and mechanistic studies of co-ordination compounds. Part 29. Synthesis and characterization of some cis-macrocyclic secondary amine complexes of ruthenium
Title | Structural and mechanistic studies of co-ordination compounds. Part 29. Synthesis and characterization of some cis-macrocyclic secondary amine complexes of ruthenium |
---|---|
Authors | |
Issue Date | 1981 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society, Dalton Transactions, 1981 n. 6, p. 1336-1341 How to Cite? |
Abstract | Under suitably controlled conditions, the reaction between trioxalatoruthenate(III), [Ru(O4C2)3]3-, and 1,4,8,11-tetra-azacyclotetradecane (L1) in the presence of an acid HX leads to the formation of the corresponding cis-[RuL1X2]+ (X = Cl or Br) in ca. 50% yield. Other complexes of the type cis-[RuL1(X)Y]+ [(X)Y = I2, (NCS)2, (Br)Cl, or oxalate] have been obtained from either the dichloro- or the dibromo-complex by metathetical procedures. The ion cis-[RuL1(NCS)2]+ can easily be reduced and the product cis-[RuL1(NCS)2]·H2O has been isolated and characterized. The reaction of [Ru(O4C2)3]3- with 1,4,8,12-tetra-azacyclopentadecane (L2) in HBr yields cis-[RuL2Br2]+, but its reactions with open-chain tetramines, 3,7-diazanonane-1,9-diamine (L3) and 4,7-diazadecane-1,10-diamine (L4), in the presence of HX (X = Cl or Br) only resulted in the formation of the corresponding trans-dihalogeno-complexes. The assignment of a cis configuration to these complexes has been made on the basis of i.r. and electronic absorption spectroscopy. The 1H n.m.r. spectrum of cis-[RuL1(NCS)2]·H2O is consistent with a cis configuration. |
Persistent Identifier | http://hdl.handle.net/10722/168258 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Poon, CK | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:16:45Z | - |
dc.date.available | 2012-10-08T03:16:45Z | - |
dc.date.issued | 1981 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 1981 n. 6, p. 1336-1341 | en_US |
dc.identifier.issn | 1472-7773 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168258 | - |
dc.description.abstract | Under suitably controlled conditions, the reaction between trioxalatoruthenate(III), [Ru(O4C2)3]3-, and 1,4,8,11-tetra-azacyclotetradecane (L1) in the presence of an acid HX leads to the formation of the corresponding cis-[RuL1X2]+ (X = Cl or Br) in ca. 50% yield. Other complexes of the type cis-[RuL1(X)Y]+ [(X)Y = I2, (NCS)2, (Br)Cl, or oxalate] have been obtained from either the dichloro- or the dibromo-complex by metathetical procedures. The ion cis-[RuL1(NCS)2]+ can easily be reduced and the product cis-[RuL1(NCS)2]·H2O has been isolated and characterized. The reaction of [Ru(O4C2)3]3- with 1,4,8,12-tetra-azacyclopentadecane (L2) in HBr yields cis-[RuL2Br2]+, but its reactions with open-chain tetramines, 3,7-diazanonane-1,9-diamine (L3) and 4,7-diazadecane-1,10-diamine (L4), in the presence of HX (X = Cl or Br) only resulted in the formation of the corresponding trans-dihalogeno-complexes. The assignment of a cis configuration to these complexes has been made on the basis of i.r. and electronic absorption spectroscopy. The 1H n.m.r. spectrum of cis-[RuL1(NCS)2]·H2O is consistent with a cis configuration. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Structural and mechanistic studies of co-ordination compounds. Part 29. Synthesis and characterization of some cis-macrocyclic secondary amine complexes of ruthenium | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9810001336 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049094034 | en_US |
dc.identifier.issue | 6 | en_US |
dc.identifier.spage | 1336 | en_US |
dc.identifier.epage | 1341 | en_US |
dc.identifier.isi | WOS:A1981LU63500018 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Poon, CK=7202673504 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 1364-5447 | - |