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Article: Photoluminescent properties and molecular structure of [{Au(PPh3)}2(μ-bbzim)] and[{Au(PPh3)}4(μ-bbzim)][ClO4] 2(bbziM = 2,2′-bibenzimidazolate)

TitlePhotoluminescent properties and molecular structure of [{Au(PPh3)}2(μ-bbzim)] and[{Au(PPh3)}4(μ-bbzim)][ClO4] 2(bbziM = 2,2′-bibenzimidazolate)
Authors
Tzeng, BCLi, DPeng, SMChe, CM
Issue Date1993
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1993 n. 15, p. 2365-2371 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9930002365
AbstractThe tetranuclear [{Au(PPh3)}4(μ-bbzim)][ClO4]2 and dinuclear [{Au(PPh3)}2(μ-bbzim)] complexes with 2,2′-bibenzimidazolate (bbzim) as bridging ligand have been characterized by X-ray crystallography. The intramolecular Au-Au separations in [{Au(PPh3)}4(μ-bbzim)][ClO4]2 are 3.157(1)-3.222(1) Å. Upon excitation at 330 nm, both complexes display intense intraligand fluorescence and phosphorescence in fluid solution at room temperature.
Persistent Identifierhttp://hdl.handle.net/10722/168243
ISSN
1472-7773
ISI Accession Number ID
WOS:A1993LT04700016

 

DC FieldValueLanguage
dc.contributor.authorTzeng, BCen_US
dc.contributor.authorLi, Den_US
dc.contributor.authorPeng, SMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:16:37Z-
dc.date.available2012-10-08T03:16:37Z-
dc.date.issued1993en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1993 n. 15, p. 2365-2371en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168243-
dc.description.abstractThe tetranuclear [{Au(PPh3)}4(μ-bbzim)][ClO4]2 and dinuclear [{Au(PPh3)}2(μ-bbzim)] complexes with 2,2′-bibenzimidazolate (bbzim) as bridging ligand have been characterized by X-ray crystallography. The intramolecular Au-Au separations in [{Au(PPh3)}4(μ-bbzim)][ClO4]2 are 3.157(1)-3.222(1) Å. Upon excitation at 330 nm, both complexes display intense intraligand fluorescence and phosphorescence in fluid solution at room temperature.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titlePhotoluminescent properties and molecular structure of [{Au(PPh3)}2(μ-bbzim)] and[{Au(PPh3)}4(μ-bbzim)][ClO4] 2(bbziM = 2,2′-bibenzimidazolate)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9930002365en_US
dc.identifier.scopuseid_2-s2.0-37049087990en_US
dc.identifier.issue15en_US
dc.identifier.spage2365en_US
dc.identifier.epage2371en_US
dc.identifier.isiWOS:A1993LT04700016-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridTzeng, BC=7003648630en_US
dc.identifier.scopusauthoridLi, D=26324923700en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.issnl1364-5447-

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