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Article: High-valent paramagnetic ruthenium(IV) complexes containing multianionic chelating ligands as efficient catalysts for alkene epoxidation; X-ray crystal structure of 2[RuIV(chbae)(PPh3)(py)]·Et 2O·2H2O [H4chbae = 1,2-bis(3,5-dichloro- 2-hydroxybenzamido)ethane; py = pyridine]

TitleHigh-valent paramagnetic ruthenium(IV) complexes containing multianionic chelating ligands as efficient catalysts for alkene epoxidation; X-ray crystal structure of 2[RuIV(chbae)(PPh3)(py)]·Et 2O·2H2O [H4chbae = 1,2-bis(3,5-dichloro- 2-hydroxybenzamido)ethane; py = pyridine]
Authors
Che, CMCheng, WKLeung, WHMak, TCW
Issue Date1987
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1987 n. 6, p. 418-419 How to Cite?
DOI: http://dx.doi.org/10.1039/C39870000418
AbstractThe reaction of 1,2-bis(3,5-dichloro-2-hydroxybenzamido)ethane (H 4chbae) with Ru(PPh3)3Cl2 yielded [RuIV(chbae)(PPh3)2] which in turn gave [RuIV(chbae)(PPh3)(py)] (py = pyridine) upon treatment with pyridine; the [RuIV(chbae)(PPh3)(py)] complex has been characterized by magnetic susceptibility measurement (μeff. = 3.08 μB) and X-ray crystallography and found to catalyse the epoxidation of alkenes in the presence of iodosylbenzene.
Persistent Identifierhttp://hdl.handle.net/10722/168242
ISSN
0022-4936
ISI Accession Number ID
WOS:A1987G595300017

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorCheng, WKen_US
dc.contributor.authorLeung, WHen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:16:37Z-
dc.date.available2012-10-08T03:16:37Z-
dc.date.issued1987en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1987 n. 6, p. 418-419en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168242-
dc.description.abstractThe reaction of 1,2-bis(3,5-dichloro-2-hydroxybenzamido)ethane (H 4chbae) with Ru(PPh3)3Cl2 yielded [RuIV(chbae)(PPh3)2] which in turn gave [RuIV(chbae)(PPh3)(py)] (py = pyridine) upon treatment with pyridine; the [RuIV(chbae)(PPh3)(py)] complex has been characterized by magnetic susceptibility measurement (μeff. = 3.08 μB) and X-ray crystallography and found to catalyse the epoxidation of alkenes in the presence of iodosylbenzene.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleHigh-valent paramagnetic ruthenium(IV) complexes containing multianionic chelating ligands as efficient catalysts for alkene epoxidation; X-ray crystal structure of 2[RuIV(chbae)(PPh3)(py)]·Et 2O·2H2O [H4chbae = 1,2-bis(3,5-dichloro- 2-hydroxybenzamido)ethane; py = pyridine]en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39870000418en_US
dc.identifier.scopuseid_2-s2.0-37049087899en_US
dc.identifier.issue6en_US
dc.identifier.spage418en_US
dc.identifier.epage419en_US
dc.identifier.isiWOS:A1987G595300017-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridCheng, WK=7402169559en_US
dc.identifier.scopusauthoridLeung, WH=7201504510en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl0022-4936-

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