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Article: A luminescent tetrameric zinc(II) complex containing the 7-azaindolate ligand. Photophysical properties and crystal structure

TitleA luminescent tetrameric zinc(II) complex containing the 7-azaindolate ligand. Photophysical properties and crystal structure
Authors
Lee, CFChin, KFPeng, SMChe, CM
Issue Date1993
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1993 n. 3, p. 467-470 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9930000467
AbstractReaction of ZnII with 7-azaindole in methanol and in the presence of triethylamine gave a tetrameric zinc(II) complex characterized by X-ray crystallography to be [Zn4O(C7H5N2)6]. The measured intramolecular Zn ⋯ Zn separations and Zn-O distances are 3.147(2)-3.209(2) and 1.903(8)-1.975(8) Å respectively. At room temperature the cluster displays intense photoluminescence at 448 nm in the solid state and 425 nm in acetonitrile. The lifetime and quantum yield of the emission are 0.1 μs and 0.17 respectively.
Persistent Identifierhttp://hdl.handle.net/10722/168229
ISSN
1472-7773
ISI Accession Number ID
WOS:A1993KL59000018

 

DC FieldValueLanguage
dc.contributor.authorLee, CFen_US
dc.contributor.authorChin, KFen_US
dc.contributor.authorPeng, SMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:16:28Z-
dc.date.available2012-10-08T03:16:28Z-
dc.date.issued1993en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1993 n. 3, p. 467-470en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168229-
dc.description.abstractReaction of ZnII with 7-azaindole in methanol and in the presence of triethylamine gave a tetrameric zinc(II) complex characterized by X-ray crystallography to be [Zn4O(C7H5N2)6]. The measured intramolecular Zn ⋯ Zn separations and Zn-O distances are 3.147(2)-3.209(2) and 1.903(8)-1.975(8) Å respectively. At room temperature the cluster displays intense photoluminescence at 448 nm in the solid state and 425 nm in acetonitrile. The lifetime and quantum yield of the emission are 0.1 μs and 0.17 respectively.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleA luminescent tetrameric zinc(II) complex containing the 7-azaindolate ligand. Photophysical properties and crystal structureen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9930000467en_US
dc.identifier.scopuseid_2-s2.0-37049082559en_US
dc.identifier.issue3en_US
dc.identifier.spage467en_US
dc.identifier.epage470en_US
dc.identifier.isiWOS:A1993KL59000018-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridLee, CF=23067853800en_US
dc.identifier.scopusauthoridChin, KF=23066279000en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.issnl1364-5447-

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