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Article: Preparation and crystal structures of cationic dienehydrido and dienyl ruthenium complexes containing N,N′,N′-trimethyl-1,4,7-triazacyclononane

TitlePreparation and crystal structures of cationic dienehydrido and dienyl ruthenium complexes containing N,N′,N′-trimethyl-1,4,7-triazacyclononane
Authors
Yang, SMCheng, WCCheung, KKChe, CMPeng, SM
Issue Date1995
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1995 n. 2, p. 227-230 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9950000227
AbstractThe reaction between [{Ru(cod)Cl2}n] (cod = cycloocta-1,5-diene) and N,N′,N″-trimethyl-1,4,7-triazacyclononane (tacn) in ethanol-water gave [Ru(tacn)(1,2,5,6-η-cod)H]ClO4 1. When tert-butyl alcohol was used as the solvent, [Ru(tacn)(1,2,3,4,5-η-C8H11)]ClO4 2 was obtained. The Ru-H moiety in 1 is characterized by a 1H NMR signal at δ -6.11 and a ν(Ru-H) stretch at 2040 Cm-1. Crystal structure analysis shows that the co-ordinated cod of 1 is in the tub form, whereas complex 2 has an η5-cyclooctadienyl ligand.
Persistent Identifierhttp://hdl.handle.net/10722/168223
ISSN
1472-7773
ISI Accession Number ID
WOS:A1995QD21200010

 

DC FieldValueLanguage
dc.contributor.authorYang, SMen_US
dc.contributor.authorCheng, WCen_US
dc.contributor.authorCheung, KKen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorPeng, SMen_US
dc.date.accessioned2012-10-08T03:16:26Z-
dc.date.available2012-10-08T03:16:26Z-
dc.date.issued1995en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1995 n. 2, p. 227-230en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168223-
dc.description.abstractThe reaction between [{Ru(cod)Cl2}n] (cod = cycloocta-1,5-diene) and N,N′,N″-trimethyl-1,4,7-triazacyclononane (tacn) in ethanol-water gave [Ru(tacn)(1,2,5,6-η-cod)H]ClO4 1. When tert-butyl alcohol was used as the solvent, [Ru(tacn)(1,2,3,4,5-η-C8H11)]ClO4 2 was obtained. The Ru-H moiety in 1 is characterized by a 1H NMR signal at δ -6.11 and a ν(Ru-H) stretch at 2040 Cm-1. Crystal structure analysis shows that the co-ordinated cod of 1 is in the tub form, whereas complex 2 has an η5-cyclooctadienyl ligand.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titlePreparation and crystal structures of cationic dienehydrido and dienyl ruthenium complexes containing N,N′,N′-trimethyl-1,4,7-triazacyclononaneen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9950000227en_US
dc.identifier.scopuseid_2-s2.0-37049080611en_US
dc.identifier.hkuros1449-
dc.identifier.issue2en_US
dc.identifier.spage227en_US
dc.identifier.epage230en_US
dc.identifier.isiWOS:A1995QD21200010-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridYang, SM=7408521494en_US
dc.identifier.scopusauthoridCheng, WC=7402169293en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US
dc.identifier.issnl1364-5447-

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