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Article: Photochemical degradation of halogenocarbons by a diphosphine-di-isocyanide bridged rhodium(I) dimer

TitlePhotochemical degradation of halogenocarbons by a diphosphine-di-isocyanide bridged rhodium(I) dimer
Authors
Che, CMLee, WM
Issue Date1986
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1986 n. 8, p. 616-617 How to Cite?
DOI: http://dx.doi.org/10.1039/C39860000616
AbstractThe synthesis and spectroscopic properties of [Rh2(dppm) 2(TMB)2]2+ [dppm=bis(diphenylphosphino)methane; TMB=2,5-dimethyl-2,5-di-isocyanohexane] and [Rh2(dppm) 2(TMB)2X2]2+ (X=Cl, Br, I) are described; excitation of an acetonitrile solution of [Rh2(dppm) 2(TMB)2]2+ at ca. 590 nm in the presence of RCl (CH2Cl2, CHCl3, or CCl4) results in the formation of [Rh2(dppm)2(TMB)2Cl 2]2+.
Persistent Identifierhttp://hdl.handle.net/10722/168219
ISSN
0022-4936
ISI Accession Number ID
WOS:A1986C060000023

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorLee, WMen_US
dc.date.accessioned2012-10-08T03:16:23Z-
dc.date.available2012-10-08T03:16:23Z-
dc.date.issued1986en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1986 n. 8, p. 616-617en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168219-
dc.description.abstractThe synthesis and spectroscopic properties of [Rh2(dppm) 2(TMB)2]2+ [dppm=bis(diphenylphosphino)methane; TMB=2,5-dimethyl-2,5-di-isocyanohexane] and [Rh2(dppm) 2(TMB)2X2]2+ (X=Cl, Br, I) are described; excitation of an acetonitrile solution of [Rh2(dppm) 2(TMB)2]2+ at ca. 590 nm in the presence of RCl (CH2Cl2, CHCl3, or CCl4) results in the formation of [Rh2(dppm)2(TMB)2Cl 2]2+.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titlePhotochemical degradation of halogenocarbons by a diphosphine-di-isocyanide bridged rhodium(I) dimeren_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39860000616en_US
dc.identifier.scopuseid_2-s2.0-37049079841en_US
dc.identifier.issue8en_US
dc.identifier.spage616en_US
dc.identifier.epage617en_US
dc.identifier.isiWOS:A1986C060000023-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridLee, WM=27167694800en_US
dc.identifier.issnl0022-4936-

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