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Article: High-valent oxo complexes of osmium as selective oxidants for cyclohexene oxidation. Complexation of the bisamide tetradentate ligand bpb to osmium and the X-ray structure of trans-[OsIII(bpb)(PPh3)Cl] [bpbH2=N,N′-bis(2′-pyridine-carboxamide)-1,2-benzene]

TitleHigh-valent oxo complexes of osmium as selective oxidants for cyclohexene oxidation. Complexation of the bisamide tetradentate ligand bpb to osmium and the X-ray structure of trans-[OsIII(bpb)(PPh3)Cl] [bpbH2=N,N′-bis(2′-pyridine-carboxamide)-1,2-benzene]
Authors
Che, CMCheng, WKMak, TCW
Issue Date1986
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1986 n. 3, p. 200-202 How to Cite?
DOI: http://dx.doi.org/10.1039/C39860000200
AbstractThe reaction of N,N′-bis(2′-pyridinecarboxamide)-1,2-benzene (bpbH2) with K2[OsO2(OH)4] yielded trans-[OsVI(bpbH2)O2]2+ which in turn gave trans-[OsIII(bpb)(PPh3)Cl] upon treatment with PPh3; the OsIII complex has been characterized by X-ray crystallography and found to catalyse the epoxidation of cyclohexene in the presence of iodosobenzene.
Persistent Identifierhttp://hdl.handle.net/10722/168201
ISSN
0022-4936
ISI Accession Number ID
WOS:A1986A128100010

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorCheng, WKen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:16:13Z-
dc.date.available2012-10-08T03:16:13Z-
dc.date.issued1986en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1986 n. 3, p. 200-202en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168201-
dc.description.abstractThe reaction of N,N′-bis(2′-pyridinecarboxamide)-1,2-benzene (bpbH2) with K2[OsO2(OH)4] yielded trans-[OsVI(bpbH2)O2]2+ which in turn gave trans-[OsIII(bpb)(PPh3)Cl] upon treatment with PPh3; the OsIII complex has been characterized by X-ray crystallography and found to catalyse the epoxidation of cyclohexene in the presence of iodosobenzene.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleHigh-valent oxo complexes of osmium as selective oxidants for cyclohexene oxidation. Complexation of the bisamide tetradentate ligand bpb to osmium and the X-ray structure of trans-[OsIII(bpb)(PPh3)Cl] [bpbH2=N,N′-bis(2′-pyridine-carboxamide)-1,2-benzene]en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39860000200en_US
dc.identifier.scopuseid_2-s2.0-37049074290en_US
dc.identifier.issue3en_US
dc.identifier.spage200en_US
dc.identifier.epage202en_US
dc.identifier.isiWOS:A1986A128100010-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridCheng, WK=36990980200en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl0022-4936-

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