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Article: Oxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide ligand

TitleOxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide ligand
Authors
Li, ZYYu, WYChe, CMPoon, CKWang, RJMak, TCW
Issue Date1992
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1992 n. 10, p. 1657-1661 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9920001657
AbstractThe synthesis and characterization of dioxoosmium(VI) complexes cis-[OsO2L] and trans-[OsO2L′] (L′ = NH2But, pyridine or 4-tert-butylpyridine), the nitrido complex [OsN(L)Cl], and imido complexes [OsL(NCOCF3)Cl(O2CCF3)] and [OsL(NPh)2] [H2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridine] are described. The crystal structures of [OsN(L)Cl] and [OsO2L(NH2But)]·0.5C6H 14 have been determined: the Os≡N and average Os=O bond distances are 1.634(5) and 1.741(5) Å, respectively.
Persistent Identifierhttp://hdl.handle.net/10722/168171
ISSN
1472-7773
ISI Accession Number ID
WOS:A1992HW16600011

 

DC FieldValueLanguage
dc.contributor.authorLi, ZYen_US
dc.contributor.authorYu, WYen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorPoon, CKen_US
dc.contributor.authorWang, RJen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:15:56Z-
dc.date.available2012-10-08T03:15:56Z-
dc.date.issued1992en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1992 n. 10, p. 1657-1661en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168171-
dc.description.abstractThe synthesis and characterization of dioxoosmium(VI) complexes cis-[OsO2L] and trans-[OsO2L′] (L′ = NH2But, pyridine or 4-tert-butylpyridine), the nitrido complex [OsN(L)Cl], and imido complexes [OsL(NCOCF3)Cl(O2CCF3)] and [OsL(NPh)2] [H2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridine] are described. The crystal structures of [OsN(L)Cl] and [OsO2L(NH2But)]·0.5C6H 14 have been determined: the Os≡N and average Os=O bond distances are 1.634(5) and 1.741(5) Å, respectively.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleOxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide liganden_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9920001657en_US
dc.identifier.scopuseid_2-s2.0-37049068709en_US
dc.identifier.issue10en_US
dc.identifier.spage1657en_US
dc.identifier.epage1661en_US
dc.identifier.isiWOS:A1992HW16600011-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridLi, ZY=7409079858en_US
dc.identifier.scopusauthoridYu, WY=7403913673en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.scopusauthoridWang, RJ=7405340385en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl1364-5447-

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