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Article: Metal-oxo photo-oxidants: Photochemical oxidation of hydrocarbons by trans-dioxo complexes of ruthenium(VI) and osmium(VI)
Title | Metal-oxo photo-oxidants: Photochemical oxidation of hydrocarbons by trans-dioxo complexes of ruthenium(VI) and osmium(VI) |
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Authors | |
Issue Date | 1988 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
Citation | Journal Of The Chemical Society, Chemical Communications, 1988 n. 2, p. 100-102 How to Cite? |
Abstract | The synthesis of trans-[RuVI(L)(O)2]Y2 (Y = PF6 or ClO4) and trans-[RuIV(L)(NCO)(O)] ClO4 {L = meso-1,2,6,10,11-pentamethyl-2,6,10-triaza[11](2,6) pyridinophane} is described; irradiation of trans-[RuVI(L)(O) 2]2+ and [OsVI(CN)4(O) 2]2- (λ > 330 nm) in presence of organic substrates yielded the corresponding oxidized organic products indicating that the (dxy)1(dπ*)1 excited states of RuVI- and OsVI-oxo complexes are reactive towards epoxidation of alkenes and to oxidation of C-H bonds. |
Persistent Identifier | http://hdl.handle.net/10722/168170 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Tang, WT | en_US |
dc.date.accessioned | 2012-10-08T03:15:56Z | - |
dc.date.available | 2012-10-08T03:15:56Z | - |
dc.date.issued | 1988 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Chemical Communications, 1988 n. 2, p. 100-102 | en_US |
dc.identifier.issn | 0022-4936 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168170 | - |
dc.description.abstract | The synthesis of trans-[RuVI(L)(O)2]Y2 (Y = PF6 or ClO4) and trans-[RuIV(L)(NCO)(O)] ClO4 {L = meso-1,2,6,10,11-pentamethyl-2,6,10-triaza[11](2,6) pyridinophane} is described; irradiation of trans-[RuVI(L)(O) 2]2+ and [OsVI(CN)4(O) 2]2- (λ > 330 nm) in presence of organic substrates yielded the corresponding oxidized organic products indicating that the (dxy)1(dπ*)1 excited states of RuVI- and OsVI-oxo complexes are reactive towards epoxidation of alkenes and to oxidation of C-H bonds. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | en_US |
dc.title | Metal-oxo photo-oxidants: Photochemical oxidation of hydrocarbons by trans-dioxo complexes of ruthenium(VI) and osmium(VI) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/C39880000100 | en_US |
dc.identifier.scopus | eid_2-s2.0-37049068682 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.spage | 100 | en_US |
dc.identifier.epage | 102 | en_US |
dc.identifier.isi | WOS:A1988L906500015 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Tang, WT=15121154000 | en_US |
dc.identifier.issnl | 0022-4936 | - |