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Article: Disproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium

TitleDisproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium
Authors
Wong, KYChe, CMYip, WHWang, RJMak, TCW
Issue Date1992
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1992 n. 8, p. 1417-1421 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9920001417
AbstractThe reaction of trans-[RuLCl2]+ (L = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) with NO2 - in water at 60 °C leads to the formation of trans-[RuL(O)Cl]+ and trans-[RuL(OH)(NO)]2+. The formation of the products can be rationalized by the disproportionation of trans-[RuL(Cl)(NO2)]+. The structures of the products have been determined by X-ray crystallography: trans-[RuL(O)Cl]ClO4, space group Pna21 (no. 33), a = 12.616(1), b = 15.421(3), c = 11.292(3) Å; Ru=O and Ru-Cl 1.75(1) and 2.435(6) Å; trans-[RuL(OH)(NO)][ClO4]2, space group Pbca (no. 61), a = 20.459(3), b = 29.16(1), c = 25.13(1) Å; average Ru-OH and Ru-NO 1.906(9) and 1.74(1) Å.
Persistent Identifierhttp://hdl.handle.net/10722/168163
ISSN
1472-7773
ISI Accession Number ID
WOS:A1992HQ62000014

 

DC FieldValueLanguage
dc.contributor.authorWong, KYen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorYip, WHen_US
dc.contributor.authorWang, RJen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:15:50Z-
dc.date.available2012-10-08T03:15:50Z-
dc.date.issued1992en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1992 n. 8, p. 1417-1421en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168163-
dc.description.abstractThe reaction of trans-[RuLCl2]+ (L = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) with NO2 - in water at 60 °C leads to the formation of trans-[RuL(O)Cl]+ and trans-[RuL(OH)(NO)]2+. The formation of the products can be rationalized by the disproportionation of trans-[RuL(Cl)(NO2)]+. The structures of the products have been determined by X-ray crystallography: trans-[RuL(O)Cl]ClO4, space group Pna21 (no. 33), a = 12.616(1), b = 15.421(3), c = 11.292(3) Å; Ru=O and Ru-Cl 1.75(1) and 2.435(6) Å; trans-[RuL(OH)(NO)][ClO4]2, space group Pbca (no. 61), a = 20.459(3), b = 29.16(1), c = 25.13(1) Å; average Ru-OH and Ru-NO 1.906(9) and 1.74(1) Å.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleDisproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous mediumen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9920001417en_US
dc.identifier.scopuseid_2-s2.0-37049067653en_US
dc.identifier.issue8en_US
dc.identifier.spage1417en_US
dc.identifier.epage1421en_US
dc.identifier.isiWOS:A1992HQ62000014-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridYip, WH=15080124700en_US
dc.identifier.scopusauthoridWang, RJ=7405340385en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US
dc.identifier.issnl1364-5447-

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