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Article: A phase transition of the adsorbed layer: High pressure effect on fatty alcohol adsorption at an oil-water interface

TitleA phase transition of the adsorbed layer: High pressure effect on fatty alcohol adsorption at an oil-water interface
Authors
Lin, MFirpo, JLMansoura, PBaret, JF
Issue Date1979
PublisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp
Citation
The Journal of Chemical Physics, 1979, v. 71 n. 5, p. 2202-2206 How to Cite?
DOI: http://dx.doi.org/10.1063/1.438551
AbstractMeasurement of the interfacial tension of fatty alcohol solutions permits determination of the amount of amphiphile adsorbed. This amount varies with both pressure and concentration. At some critical value, the interfacial solution splits into two phases. In the dilute phase, the adsorbed molecules are solvated by the oil whereas in the condensed phase there is no solvent interspersed between the aliphatic chains. A thermodynamical analysis of this two-dimensional phase transition is given assuming the interfacial solution to be regular. © 1979 American Institute of Physics.
Persistent Identifierhttp://hdl.handle.net/10722/168156
ISSN
0021-9606
2023 Impact Factor: 3.1
2023 SCImago Journal Rankings: 1.101
ISI Accession Number ID
WOS:A1979HK47800029

 

DC FieldValueLanguage
dc.contributor.authorLin, Men_US
dc.contributor.authorFirpo, JLen_US
dc.contributor.authorMansoura, Pen_US
dc.contributor.authorBaret, JFen_US
dc.date.accessioned2012-10-08T03:15:46Z-
dc.date.available2012-10-08T03:15:46Z-
dc.date.issued1979en_US
dc.identifier.citationThe Journal of Chemical Physics, 1979, v. 71 n. 5, p. 2202-2206-
dc.identifier.issn0021-9606en_US
dc.identifier.urihttp://hdl.handle.net/10722/168156-
dc.description.abstractMeasurement of the interfacial tension of fatty alcohol solutions permits determination of the amount of amphiphile adsorbed. This amount varies with both pressure and concentration. At some critical value, the interfacial solution splits into two phases. In the dilute phase, the adsorbed molecules are solvated by the oil whereas in the condensed phase there is no solvent interspersed between the aliphatic chains. A thermodynamical analysis of this two-dimensional phase transition is given assuming the interfacial solution to be regular. © 1979 American Institute of Physics.en_US
dc.languageengen_US
dc.publisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jspen_US
dc.relation.ispartofThe Journal of Chemical Physicsen_US
dc.rightsCopyright 1979 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in The Journal of Chemical Physics, 1979, v. 71 n. 5, p. 2202-2206 and may be found at https://doi.org/10.1063/1.438551-
dc.titleA phase transition of the adsorbed layer: High pressure effect on fatty alcohol adsorption at an oil-water interfaceen_US
dc.typeArticleen_US
dc.identifier.emailLin, M:mcllin@hkucc.hku.hken_US
dc.identifier.authorityLin, M=rp00746en_US
dc.description.naturepublished_or_final_versionen_US
dc.identifier.doi10.1063/1.438551-
dc.identifier.scopuseid_2-s2.0-36749111992en_US
dc.identifier.volume71en_US
dc.identifier.issue5en_US
dc.identifier.spage2202en_US
dc.identifier.epage2206en_US
dc.identifier.isiWOS:A1979HK47800029-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridLin, M=7404816359en_US
dc.identifier.scopusauthoridFirpo, JL=6603421435en_US
dc.identifier.scopusauthoridMansoura, P=23031357600en_US
dc.identifier.scopusauthoridBaret, JF=6701359097en_US
dc.identifier.issnl0021-9606-

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