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- Publisher Website: 10.1021/ic061711m
- Scopus: eid_2-s2.0-34347268820
- PMID: 17488068
- WOS: WOS:000246907800019
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Article: Multiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networks
Title | Multiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networks |
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Authors | |
Issue Date | 2007 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
Citation | Inorganic Chemistry, 2007, v. 46 n. 12, p. 4844-4849 How to Cite? |
Abstract | We introduce the 1,2,3-tris(organylthiophenyl) group as a symmetrical, multidentate chelation link for building coordination networks. For this, zinc(II) 5,10,15,20-tetrakis[3′,4′,5′-tris(methylthio)phenyl] porphyrin was synthesized and integrated into a two-dimensional network via coordination with BiBr 3. The coordination link exhibits an unusually complex bonding pattern, involving six S atoms from two neighboring ligands that form multiple Bi-S interactions (distances ranging from 3.08 to 3.63 Å) with a dimerlike unit of Bi 2Br 6. The electronic interaction between the porphyrin center and the Bi 2Br 6 block was illustrated by the diffuse-reflectance spectrum of the network compound, in which a modest red-shifted feature at 1.8 eV was seen (while the Q-band absorption of the metalloporphyrin core continues to be dominant at 1.9 eV). © 2007 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/168125 |
ISSN | 2021 Impact Factor: 5.436 2020 SCImago Journal Rankings: 1.348 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Li, K | en_HK |
dc.contributor.author | Huang, G | en_HK |
dc.contributor.author | Xu, Z | en_HK |
dc.contributor.author | Zhang, M | en_HK |
dc.contributor.author | Zeller, M | en_HK |
dc.contributor.author | Hunter, AD | en_HK |
dc.contributor.author | Chui, SSY | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.contributor.author | Wong, WY | en_HK |
dc.date.accessioned | 2012-10-08T03:15:24Z | - |
dc.date.available | 2012-10-08T03:15:24Z | - |
dc.date.issued | 2007 | en_HK |
dc.identifier.citation | Inorganic Chemistry, 2007, v. 46 n. 12, p. 4844-4849 | en_HK |
dc.identifier.issn | 0020-1669 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/168125 | - |
dc.description.abstract | We introduce the 1,2,3-tris(organylthiophenyl) group as a symmetrical, multidentate chelation link for building coordination networks. For this, zinc(II) 5,10,15,20-tetrakis[3′,4′,5′-tris(methylthio)phenyl] porphyrin was synthesized and integrated into a two-dimensional network via coordination with BiBr 3. The coordination link exhibits an unusually complex bonding pattern, involving six S atoms from two neighboring ligands that form multiple Bi-S interactions (distances ranging from 3.08 to 3.63 Å) with a dimerlike unit of Bi 2Br 6. The electronic interaction between the porphyrin center and the Bi 2Br 6 block was illustrated by the diffuse-reflectance spectrum of the network compound, in which a modest red-shifted feature at 1.8 eV was seen (while the Q-band absorption of the metalloporphyrin core continues to be dominant at 1.9 eV). © 2007 American Chemical Society. | en_HK |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_HK |
dc.relation.ispartof | Inorganic Chemistry | en_HK |
dc.subject.mesh | Bismuth - Chemistry | en_US |
dc.subject.mesh | Ligands | en_US |
dc.subject.mesh | Macromolecular Substances - Chemistry | en_US |
dc.subject.mesh | Metalloporphyrins - Chemistry | en_US |
dc.subject.mesh | Spectrum Analysis | en_US |
dc.subject.mesh | Sulfides - Chemistry | en_US |
dc.title | Multiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networks | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Chui, SSY: chuissy@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Chui, SSY=rp00686 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ic061711m | en_HK |
dc.identifier.pmid | 17488068 | - |
dc.identifier.scopus | eid_2-s2.0-34347268820 | en_HK |
dc.identifier.hkuros | 137045 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-34347268820&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 46 | en_HK |
dc.identifier.issue | 12 | en_HK |
dc.identifier.spage | 4844 | en_HK |
dc.identifier.epage | 4849 | en_HK |
dc.identifier.isi | WOS:000246907800019 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Li, K=55487992100 | en_HK |
dc.identifier.scopusauthorid | Huang, G=36984730800 | en_HK |
dc.identifier.scopusauthorid | Xu, Z=9843801700 | en_HK |
dc.identifier.scopusauthorid | Zhang, M=36072753300 | en_HK |
dc.identifier.scopusauthorid | Zeller, M=8518298000 | en_HK |
dc.identifier.scopusauthorid | Hunter, AD=7402779700 | en_HK |
dc.identifier.scopusauthorid | Chui, SSY=8297453100 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.scopusauthorid | Wong, WY=7403972153 | en_HK |
dc.identifier.issnl | 0020-1669 | - |