File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1039/A802279H
- Scopus: eid_2-s2.0-33749099789
- WOS: WOS:000075954300017
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Synthesis, structure and spectroscopic properties of [Cu3(μ-dpnapy)3-(CH3CN)][ClO4]3·CH3CN(dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom array
Title | Synthesis, structure and spectroscopic properties of [Cu3(μ-dpnapy)3-(CH3CN)][ClO4]3·CH3CN(dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom array |
---|---|
Authors | |
Issue Date | 1998 |
Citation | Journal Of The Chemical Society - Dalton Transactions, 1998 n. 17, p. 2867-2871 How to Cite? |
Abstract | The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I has been examined. Reaction of [Cu(CH 3CN) 4][ClO 4] with dpnapy in CH 3CN afforded [Cu 3(μ-dpnapy) 3(CH 3CN)][ClO 4] 3 1[ClO 4] 3. The crystal structure of 1[ClO 4] 3·CH 3CN reveals a linear Cu-Cu-Cu array with both trigonal and tetrahedral co-ordination modes for the copper atoms. The intramolecular Cu-Cu distances of 2.449(2) and 2.721(2) Å suggest that only two of the copper atoms have a bonding interaction. Complex 1 reacts with triphenylphosphine (PPh 3) and 2,2′-bipyridine (bpy) to give [Cu(bpy)(dpnapy) 2][ClO 4] 2[ClO 4] and [Cu 2(μ-dpnapy) 3][ClO 4] 2 3[ClO 4] 2, respectively. Spectroscopic properties of the complexes have been examined. |
Persistent Identifier | http://hdl.handle.net/10722/168051 |
ISSN | |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chan, WH | en_US |
dc.contributor.author | Peng, SM | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:14:34Z | - |
dc.date.available | 2012-10-08T03:14:34Z | - |
dc.date.issued | 1998 | en_US |
dc.identifier.citation | Journal Of The Chemical Society - Dalton Transactions, 1998 n. 17, p. 2867-2871 | en_US |
dc.identifier.issn | 0300-9246 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168051 | - |
dc.description.abstract | The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I has been examined. Reaction of [Cu(CH 3CN) 4][ClO 4] with dpnapy in CH 3CN afforded [Cu 3(μ-dpnapy) 3(CH 3CN)][ClO 4] 3 1[ClO 4] 3. The crystal structure of 1[ClO 4] 3·CH 3CN reveals a linear Cu-Cu-Cu array with both trigonal and tetrahedral co-ordination modes for the copper atoms. The intramolecular Cu-Cu distances of 2.449(2) and 2.721(2) Å suggest that only two of the copper atoms have a bonding interaction. Complex 1 reacts with triphenylphosphine (PPh 3) and 2,2′-bipyridine (bpy) to give [Cu(bpy)(dpnapy) 2][ClO 4] 2[ClO 4] and [Cu 2(μ-dpnapy) 3][ClO 4] 2 3[ClO 4] 2, respectively. Spectroscopic properties of the complexes have been examined. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Journal of the Chemical Society - Dalton Transactions | en_US |
dc.title | Synthesis, structure and spectroscopic properties of [Cu3(μ-dpnapy)3-(CH3CN)][ClO4]3·CH3CN(dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom array | en_US |
dc.type | Article | en_US |
dc.identifier.email | Chan, WH:waichan@hku.hk | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Chan, WH=rp00667 | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/A802279H | - |
dc.identifier.scopus | eid_2-s2.0-33749099789 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33749099789&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.issue | 17 | en_US |
dc.identifier.spage | 2867 | en_US |
dc.identifier.epage | 2871 | en_US |
dc.identifier.isi | WOS:000075954300017 | - |
dc.identifier.scopusauthorid | Chan, WH=13310083000 | en_US |
dc.identifier.scopusauthorid | Peng, SM=35464852200 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 0300-9246 | - |