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- Publisher Website: 10.1039/DT9960004019
- Scopus: eid_2-s2.0-33748646998
- WOS: WOS:A1996VR24800018
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Article: Synthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2]
Title | Synthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] |
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Authors | |
Issue Date | 1996 |
Citation | Journal Of The Chemical Society - Dalton Transactions, 1996 n. 20, p. 4019-4022 How to Cite? |
Abstract | A series of luminescent dinuclear gold(I) thiolates, [Au2{Ph2PN(R)PPh2}(SR′)2] (R = C6H11, R′ = C6H4F-p, C6H4Cl-p, C6H4Me-p; R = Ph, R′ = C6H4Me-p; R = Prn, R′ = C6H4Me-p; R = Pri, R′ = C6H4Me-p) have been synthesized and their photophysical properties studied. The crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] has been determined. These complexes have been shown to exhibit low-energy emission at ca. 600 nm, attributed to a ligand-to-metal charge transfer (thiolate to AuI) origin. |
Persistent Identifier | http://hdl.handle.net/10722/168045 |
ISSN | |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Chan, CL | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:14:30Z | - |
dc.date.available | 2012-10-08T03:14:30Z | - |
dc.date.issued | 1996 | en_US |
dc.identifier.citation | Journal Of The Chemical Society - Dalton Transactions, 1996 n. 20, p. 4019-4022 | en_US |
dc.identifier.issn | 0300-9246 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168045 | - |
dc.description.abstract | A series of luminescent dinuclear gold(I) thiolates, [Au2{Ph2PN(R)PPh2}(SR′)2] (R = C6H11, R′ = C6H4F-p, C6H4Cl-p, C6H4Me-p; R = Ph, R′ = C6H4Me-p; R = Prn, R′ = C6H4Me-p; R = Pri, R′ = C6H4Me-p) have been synthesized and their photophysical properties studied. The crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] has been determined. These complexes have been shown to exhibit low-energy emission at ca. 600 nm, attributed to a ligand-to-metal charge transfer (thiolate to AuI) origin. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Journal of the Chemical Society - Dalton Transactions | en_US |
dc.title | Synthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/DT9960004019 | - |
dc.identifier.scopus | eid_2-s2.0-33748646998 | en_US |
dc.identifier.hkuros | 21666 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33748646998&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.issue | 20 | en_US |
dc.identifier.spage | 4019 | en_US |
dc.identifier.epage | 4022 | en_US |
dc.identifier.isi | WOS:A1996VR24800018 | - |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Chan, CL=7404813631 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 0300-9246 | - |