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Article: Bis(aliphatic amine)ruthenium(II) porphyrins synthesis, spectroscopy and crystal structure
Title | Bis(aliphatic amine)ruthenium(II) porphyrins synthesis, spectroscopy and crystal structure |
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Authors | |
Keywords | Aliphatic Amine Characterizeation Crystal Structure Determination Ruthenium Porphyrin Synthesis |
Issue Date | 1997 |
Citation | Chinese Journal Of Inorganic Chemistry, 1997, v. 13 n. 2, p. 135-145 How to Cite? |
Abstract | The synthesis, characterization and reactivities of a series of ruthenium porphyrins including Ru1 (Por) (H2NR)2 and Ru1 (Por) (HNR2)2 [Por = tetraphenyl porphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl) porphyrinato (4-Cl-TPP); R=tert-butyl, isopropyl, cyclohexyl, n-octyl, n-dodecyl, R′ = methyl, ethyl are described. The reaction of Ru (Por) (CO) (MeOH) with m-chloroperoxylbenzoic acid(m-CPBA) followed by treatment of the reaction mixture with excess aliphatic amines readily gave bis (aliphatic amine) ruthenium (II) porphyrins in high yields. All the new complexes have been characterized by 1H NMR, IR, and UV-Visible spectroscopy. The X-ray crystal structure of Ru(TTP) (H2NBu1)2 has been determined. The Ru-N(Por) and Ru-N (H2NBu1) distances in Ru(TTP) (H2NBu1)2 are 0. 2041 nm and 0. 2175 nm, respectively. |
Persistent Identifier | http://hdl.handle.net/10722/167991 |
ISSN | 2023 Impact Factor: 0.8 2023 SCImago Journal Rankings: 0.192 |
References |
DC Field | Value | Language |
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dc.contributor.author | Li, Z | en_US |
dc.contributor.author | Che, C | en_US |
dc.date.accessioned | 2012-10-08T03:13:50Z | - |
dc.date.available | 2012-10-08T03:13:50Z | - |
dc.date.issued | 1997 | en_US |
dc.identifier.citation | Chinese Journal Of Inorganic Chemistry, 1997, v. 13 n. 2, p. 135-145 | en_US |
dc.identifier.issn | 1001-4861 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167991 | - |
dc.description.abstract | The synthesis, characterization and reactivities of a series of ruthenium porphyrins including Ru1 (Por) (H2NR)2 and Ru1 (Por) (HNR2)2 [Por = tetraphenyl porphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl) porphyrinato (4-Cl-TPP); R=tert-butyl, isopropyl, cyclohexyl, n-octyl, n-dodecyl, R′ = methyl, ethyl are described. The reaction of Ru (Por) (CO) (MeOH) with m-chloroperoxylbenzoic acid(m-CPBA) followed by treatment of the reaction mixture with excess aliphatic amines readily gave bis (aliphatic amine) ruthenium (II) porphyrins in high yields. All the new complexes have been characterized by 1H NMR, IR, and UV-Visible spectroscopy. The X-ray crystal structure of Ru(TTP) (H2NBu1)2 has been determined. The Ru-N(Por) and Ru-N (H2NBu1) distances in Ru(TTP) (H2NBu1)2 are 0. 2041 nm and 0. 2175 nm, respectively. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Chinese Journal of Inorganic Chemistry | en_US |
dc.subject | Aliphatic Amine | en_US |
dc.subject | Characterizeation | en_US |
dc.subject | Crystal Structure Determination | en_US |
dc.subject | Ruthenium Porphyrin | en_US |
dc.subject | Synthesis | en_US |
dc.title | Bis(aliphatic amine)ruthenium(II) porphyrins synthesis, spectroscopy and crystal structure | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, C:cmche@hku.hk | en_US |
dc.identifier.authority | Che, C=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.scopus | eid_2-s2.0-3042894684 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-3042894684&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 13 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.spage | 135 | en_US |
dc.identifier.epage | 145 | en_US |
dc.identifier.scopusauthorid | Li, Z=7409079858 | en_US |
dc.identifier.scopusauthorid | Che, C=7102442791 | en_US |
dc.identifier.issnl | 1001-4861 | - |