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Article: Synthesis, photophysics and binding studies of Pt(II) alkynyl terpyridine complexes with crown ether pendant. Potential luminescent sensors for metal ions
Title | Synthesis, photophysics and binding studies of Pt(II) alkynyl terpyridine complexes with crown ether pendant. Potential luminescent sensors for metal ions |
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Authors | |
Issue Date | 2005 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/jm/index.asp |
Citation | Journal Of Materials Chemistry, 2005, v. 15 n. 27-28, p. 2714-2720 How to Cite? |
Abstract | Two crown ether-containing platinum(II) alkynyl terpyridine complexes, [Pt(tpy)(C≡C-benzo-15-crown-5)]OTf (1) and [Pt(tpy)(C≡C-N-phenylaza- 15-crown-5)]OTf (2) (tpy = 2,2′:6′,2″-terpyridine), have been synthesized and characterized. UV-vis spectrophotometric, emission and 'H NMR titration methods were employed to investigate their ion-binding properties. Complex 1 was found to show luminescence enhancement upon binding of Mg 2+ and Ca2+ ions to its crown cavity. © The Royal Society of Chemistry 2005. |
Persistent Identifier | http://hdl.handle.net/10722/167943 |
ISSN | 2013 Impact Factor: 6.626 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Tang, WS | en_US |
dc.contributor.author | Lu, XX | en_US |
dc.contributor.author | Wong, KMC | en_US |
dc.contributor.author | Yam, VWW | en_US |
dc.date.accessioned | 2012-10-08T03:13:13Z | - |
dc.date.available | 2012-10-08T03:13:13Z | - |
dc.date.issued | 2005 | en_US |
dc.identifier.citation | Journal Of Materials Chemistry, 2005, v. 15 n. 27-28, p. 2714-2720 | en_US |
dc.identifier.issn | 0959-9428 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167943 | - |
dc.description.abstract | Two crown ether-containing platinum(II) alkynyl terpyridine complexes, [Pt(tpy)(C≡C-benzo-15-crown-5)]OTf (1) and [Pt(tpy)(C≡C-N-phenylaza- 15-crown-5)]OTf (2) (tpy = 2,2′:6′,2″-terpyridine), have been synthesized and characterized. UV-vis spectrophotometric, emission and 'H NMR titration methods were employed to investigate their ion-binding properties. Complex 1 was found to show luminescence enhancement upon binding of Mg 2+ and Ca2+ ions to its crown cavity. © The Royal Society of Chemistry 2005. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/jm/index.asp | en_US |
dc.relation.ispartof | Journal of Materials Chemistry | en_US |
dc.title | Synthesis, photophysics and binding studies of Pt(II) alkynyl terpyridine complexes with crown ether pendant. Potential luminescent sensors for metal ions | en_US |
dc.type | Article | en_US |
dc.identifier.email | Wong, KMC:wongmc@hku.hk | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Wong, KMC=rp00809 | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/b501644d | en_US |
dc.identifier.scopus | eid_2-s2.0-22944455522 | en_US |
dc.identifier.hkuros | 103401 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-22944455522&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 15 | en_US |
dc.identifier.issue | 27-28 | en_US |
dc.identifier.spage | 2714 | en_US |
dc.identifier.epage | 2720 | en_US |
dc.identifier.isi | WOS:000230431900011 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Tang, WS=8662866700 | en_US |
dc.identifier.scopusauthorid | Lu, XX=7404839171 | en_US |
dc.identifier.scopusauthorid | Wong, KMC=8061067200 | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.issnl | 0959-9428 | - |