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Article: Bond selective electronic excitation in IC2H4C2F4I investigated by resonance Raman spectroscopy

TitleBond selective electronic excitation in IC2H4C2F4I investigated by resonance Raman spectroscopy
Authors
Kwok, WMFuss, WPhillips, DL
Issue Date1996
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1996, v. 261 n. 6, p. 685-690 How to Cite?
DOI: http://dx.doi.org/10.1016/0009-2614(96)01007-X
AbstractWe report preliminary A-band resonance Raman spectra of IC 2H 4C 2F 4I in order to investigate bond selective electronic excitation and short-time photodissociation dynamics associated with the C-I bond cleavage. The resonance Raman spectra have most of their intensity in peaks tentatively assigned as fundamentals and only a moderate amount of intensity in overtones and combination bands. The resonance Raman intensity patterns in conjunction with results of other iodoalkanes suggest that the C-I bond cleavage has a multidimensional character which is probably greater for C-I bond cleavage at the CF 2-I end of the molecule than at the CH 2-I end of the molecule.
Persistent Identifierhttp://hdl.handle.net/10722/167905
ISSN
0009-2614
2021 Impact Factor: 2.719
2020 SCImago Journal Rankings: 0.509
ISI Accession Number ID
WOS:A1996VP78600013
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorKwok, WMen_US
dc.contributor.authorFuss, Wen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:12:46Z-
dc.date.available2012-10-08T03:12:46Z-
dc.date.issued1996en_US
dc.identifier.citationChemical Physics Letters, 1996, v. 261 n. 6, p. 685-690en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/167905-
dc.description.abstractWe report preliminary A-band resonance Raman spectra of IC 2H 4C 2F 4I in order to investigate bond selective electronic excitation and short-time photodissociation dynamics associated with the C-I bond cleavage. The resonance Raman spectra have most of their intensity in peaks tentatively assigned as fundamentals and only a moderate amount of intensity in overtones and combination bands. The resonance Raman intensity patterns in conjunction with results of other iodoalkanes suggest that the C-I bond cleavage has a multidimensional character which is probably greater for C-I bond cleavage at the CF 2-I end of the molecule than at the CH 2-I end of the molecule.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleBond selective electronic excitation in IC2H4C2F4I investigated by resonance Raman spectroscopyen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0009-2614(96)01007-Xen_US
dc.identifier.scopuseid_2-s2.0-16144366474en_US
dc.identifier.hkuros21543-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-16144366474&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume261en_US
dc.identifier.issue6en_US
dc.identifier.spage685en_US
dc.identifier.epage690en_US
dc.identifier.isiWOS:A1996VP78600013-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridKwok, WM=7103129332en_US
dc.identifier.scopusauthoridFuss, W=7005082313en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.issnl0009-2614-

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