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Article: High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)
Title | High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) |
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Authors | |
Issue Date | 1985 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
Citation | Journal Of The Chemical Society, Chemical Communications, 1985 n. 14, p. 986-988 How to Cite? |
Abstract | full title:High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[Ru VI(15-tmc) O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) The X-ray crystal structures of trans-[Ru VI(15-tmc)O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9, 13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) Å respectively, appear to be insensitive to the ring size of the macrocycle. |
Persistent Identifier | http://hdl.handle.net/10722/167897 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Mak, TCW | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Wong, KY | en_US |
dc.date.accessioned | 2012-10-08T03:12:41Z | - |
dc.date.available | 2012-10-08T03:12:41Z | - |
dc.date.issued | 1985 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Chemical Communications, 1985 n. 14, p. 986-988 | en_US |
dc.identifier.issn | 0022-4936 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167897 | - |
dc.description.abstract | full title:High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[Ru VI(15-tmc) O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) The X-ray crystal structures of trans-[Ru VI(15-tmc)O 2](ClO 4) 2 (15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI(16-tmc)O 2](ClO 4) 2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9, 13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) Å respectively, appear to be insensitive to the ring size of the macrocycle. | en_US |
dc.language | eng | en_US |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | en_US |
dc.title | High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/C39850000986 | - |
dc.identifier.scopus | eid_2-s2.0-1542355665 | en_US |
dc.identifier.issue | 14 | en_US |
dc.identifier.spage | 986 | en_US |
dc.identifier.epage | 988 | en_US |
dc.identifier.isi | WOS:A1985AMG0800034 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Mak, TCW=35230525700 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Wong, KY=7404760030 | en_US |
dc.identifier.issnl | 0022-4936 | - |