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Article: Structural preference in complexes containing both double-face and single-face π-acceptor ligands

TitleStructural preference in complexes containing both double-face and single-face π-acceptor ligands
Authors
Han Lam, WLin, Z
KeywordsCompetition For Π-Backdonation
Metal-Alkene Complexes
Metal-Alkenyl Complexes
Metal-Boryl Complexes
Metal-Silane Complexes
Issue Date2001
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 2001, v. 635 n. 1-2, p. 84-91 How to Cite?
DOI: http://dx.doi.org/10.1016/S0022-328X(01)00816-6
AbstractThe development of the Dewar-Chatt-Duncanson model has a great impact on coordination/organometallic chemistry in terms of understanding the structure and bonding in metal complexes containing π-accepting ligands. The majority of π-acceptor ligands can be categorized into two types: double-face and single-face π-accepting ligands. Metal complexes containing both single-face and double-face π-accepting ligands show unique structural preferences. In this paper, the structural consequence for these complexes will be discussed with the aid of density functional theory calculations. Examples include η1-alkenyl, η2-silane, η2-alkene and boryl octahedral complexes. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/167827
ISSN
0022-328X
2023 Impact Factor: 2.1
2023 SCImago Journal Rankings: 0.359
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorHan Lam, Wen_US
dc.contributor.authorLin, Zen_US
dc.date.accessioned2012-10-08T03:12:00Z-
dc.date.available2012-10-08T03:12:00Z-
dc.date.issued2001en_US
dc.identifier.citationJournal Of Organometallic Chemistry, 2001, v. 635 n. 1-2, p. 84-91en_US
dc.identifier.issn0022-328Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/167827-
dc.description.abstractThe development of the Dewar-Chatt-Duncanson model has a great impact on coordination/organometallic chemistry in terms of understanding the structure and bonding in metal complexes containing π-accepting ligands. The majority of π-acceptor ligands can be categorized into two types: double-face and single-face π-accepting ligands. Metal complexes containing both single-face and double-face π-accepting ligands show unique structural preferences. In this paper, the structural consequence for these complexes will be discussed with the aid of density functional theory calculations. Examples include η1-alkenyl, η2-silane, η2-alkene and boryl octahedral complexes. © 2001 Elsevier Science B.V.en_US
dc.languageengen_US
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.subjectCompetition For Π-Backdonationen_US
dc.subjectMetal-Alkene Complexesen_US
dc.subjectMetal-Alkenyl Complexesen_US
dc.subjectMetal-Boryl Complexesen_US
dc.subjectMetal-Silane Complexesen_US
dc.titleStructural preference in complexes containing both double-face and single-face π-acceptor ligandsen_US
dc.typeArticleen_US
dc.identifier.emailHan Lam, W:chsue@hku.hken_US
dc.identifier.authorityHan Lam, W=rp00719en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0022-328X(01)00816-6en_US
dc.identifier.scopuseid_2-s2.0-0042871280en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0042871280&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume635en_US
dc.identifier.issue1-2en_US
dc.identifier.spage84en_US
dc.identifier.epage91en_US
dc.publisher.placeSwitzerlanden_US
dc.identifier.scopusauthoridHan Lam, W=26642862800en_US
dc.identifier.scopusauthoridLin, Z=7404230177en_US
dc.identifier.issnl0022-328X-

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